ホームMCPワークベンチSkills
ホームワークベンチ通知マイページ
llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.8.0
  1. ホーム
  2. /化合物

ペルオキソ二硫酸ジナトリウム

Sodium Persulfate

HCID 62655
ノートを作成反応を作成見積依頼を出す
印刷プレビュー
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
7775-27-1
標準SMILES
O=S(=O)([O-])OOS(=O)(=O)[O-].[Na+].[Na+]
InChIKey
CHQMHPLRPQMAMX-UHFFFAOYSA-L
分子式
Na2S2O8
平均分子量
238.11 g/mol
単同位体質量
237.88299752

概要

Sodium persulfate appears as a white crystalline solid. Very irritating to skin and eyes. May be toxic by skin absorption. Used as a bleaching agent.

名称と識別子

優先名称
Sodium Persulfate
IUPAC
disodium;sulfonatooxy sulfate
現地名
ペルオキソ二硫酸ジナトリウム
英語名
Sodium persulfate
分子式
Na2O8S2
分子量
238.1

名称と別名

Sodium persulfate7775-27-1Sodium peroxydisulfateSodium peroxodisulfatePeroxydisulfuric acid, disodium saltPersulfate de sodiumDTXSID4029698J49FYF16JEDisodium peroxydisulfatePeroxydisulfuric acid (((HO)S(O)2)2O2), disodium saltORISTAR SPDISODIUM PEROXODISULFATE
名称をさらに表示
ペルオキソ二硫酸ジナトリウムペルオキソ二硫酸ナトリウムペルオキソ二硫酸二ナトリウム過硫酸ナトリウムペルオキシ二硫酸二ナトリウムペルオキソ二硫酸ナトリウム 過硫酸ナトリウム過硫酸ナトリウム PURUM P.A.,≥99.0% (RT)過硫酸ナトリウム REAGENT GRADE,≥98%Na2S2O8SODIUM PERSULPHATEPERSULPHATESpersulfatedesodiumSodiumPersulphateGrNatriumperoxodisulfatSodiumPersulphate,>98%
DTXCID009698Peroxydisulfuric acid (((HO)S(O)2)2O2), sodium salt (1:2)SODIUM PERSULFATE (NA2S2O8)RefChem:184069231-892-1Disodium peroxodisulphatedisodium;sulfonatooxy sulfatePersulfate de sodium [French]

データベース識別子

CAS
7775-27-1
PubChem CID
62655
DTXSID
DTXSID4029698
ChEMBL
CHEMBL502764
UNII
J49FYF16JE
EC Number
231-892-1

物性

構造計算による物性

極性表面積
150 Ų
水素結合供与体数
0
水素結合受容体数
8
回転可能結合数
1
重原子数
12
形式電荷
0
複雑度
206

実験および物理化学的性質

Chemical Classes · 2 件

Other Classes -> Inorganic Oxidizing Agents

Reactive agents - 1st degree

Cosmetics · 2 件

Cosmetic ingredients (Sodium Persulfate) -> CIR (Cosmetic Ingredient Review)

Oxidising

Density · 2 件

1.1 g/cm³

2.4 @25 °C

SolubilitySolubility in water, g/100ml at 20 °C: 55.6
Decomposition180 °C
Vapor Density1.1
Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Physical Description · 5 件

Sodium persulfate appears as a white crystalline solid. Very irritating to skin and eyes. May be toxic by skin absorption. Used as a bleaching agent.

Dry Powder; Large Crystals; Liquid; Other Solid

White, solid; [Merck Index] Hygroscopic; [CHEMINFO] White odorless crystalline solid; [MSDSonline]

WHITE CRYSTALS OR POWDER.

White crystalline solid.

物理化学的性質

安全と法規制

安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 1.3% (42 of 3253) of reports.

Danger

H272 (94%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P233, P260, P261, P264, P264+P265, P270, P271, P272, P280, P284, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P370+P378, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 3253 reports by companies from 49 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

危険有害性情報

Regulatory Information · 5 件

Chemical: Peroxydisulfuric acid ([(HO)S(O)2]2O2), sodium salt (1:2)

Peroxydisulfuric acid ([(HO)S(O)2]2O2), sodium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Peroxydisulfuric acid ([(HO)S(O)2]2O2), sodium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 20-12-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/14767

Peroxydisulfuric acid, disodium salt: HSNO Approval: HSR001357 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Peroxydisulfuric acid (((HO)S(O)2)2O2), disodium salt: Environment tier I assessment
DOT LabelOxidizer
Fire Hazards · 3 件

Excerpt from ERG Guide 140 [Oxidizers]:

CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).

化学と産業

用途と製造

Uses · 3 件

CIR ingredient: Sodium Persulfate

Used as a bleaching and oxidizing agent and polymerization catalyst; [Merck Index] Used in battery depolarizers; [Hawley] Used extensively for hair lightening and decolorizing; [eChemPortal: NICNAS]

Battery Manufacturing [Category: Industry]

U.S. Production2023: 850,000 - <1,000,000 lb
Consumer UsesPolymerization promoter
Industry UsesPlasticizer
Household ProductsInformation on 11 consumer products that contain Sodium persulfate in the following categories is provided:
Use Classification · 3 件

EPA Safer Chemical Functional Use Classes -> Oxidants and Oxidant Stabilizers

Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern

Cosmetics -> Oxidising

General Manufacturing Information · 2 件

Textiles, apparel, and leather manufacturing

Peroxydisulfuric acid ([(HO)S(O)2]2O2), sodium salt (1:2): ACTIVE

応用分野 · 4 件

用途合成樹脂重合媒、繊維の糊抜剤、金属の表面処理剤、試薬(酸化剤)など

用途漂白酸化剤、合成樹脂などの重合開始剤

使用Bleaching and oxidizing agent; promoter for emulsion polymerization reactions.

一般的な説明A white crystalline solid. Very irritating to skin and eyes. May be toxic by skin absorption. Used as a bleaching agent.

上流・下流製品情報

関連反応

113 件
反応記録を作成
HRID 47191 の反応式
HRID 47191反応物としてuspto-grants-2004_03
HRID 49213 の反応式
HRID 49213反応物としてuspto-grants-2004_03
HRID 65439 の反応式
HRID 65439反応物としてuspto-grants-1986_09
HRID 83936 の反応式
HRID 83936反応物としてuspto-grants-2014_09
HRID 83937 の反応式
HRID 83937反応物としてuspto-grants-2014_09
HRID 83938 の反応式
HRID 83938反応物としてuspto-grants-2014_09
HRID 83939 の反応式
HRID 83939反応物としてuspto-grants-2014_09
HRID 83940 の反応式
HRID 83940反応物としてuspto-grants-2014_09
1 / 15 ページ

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
その他の操作
ノートを作成反応を作成見積依頼を出す
融点
100 °C · 100 °C
比重(密度)
2 · 2,4 g/cm3
蒸気圧
0 Pa · 0Pa at 25℃
屈折率
1.43 · 1.43
貯蔵温度
15 °C · Store at +15°C to +25°C.
溶解性
2 O: · H2O: 1M at20℃、透明、無色
外見
個体
比重
2.4 · 2.4
色
白から黄色
PH
3.5 · 3.5-3.8 (100g/l, H2O, 20℃)
臭い (Odor)
無臭
水溶解度
550 g/L · 550g/L(20℃)
Merck
14 · 14,8656
安定性
不安定。強力な酸化剤。可燃物に触れると、火災の原因となることがあります。可燃性物質、強力な還元剤、強塩基、アルコール、アルミニウム、マグネシウムとの混和性。防湿。
化粧品成分の機能
酸化
InChI
1S/2Na.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2
InChIKey
CHQMHPLRPQMAMX-UHFFFAOYSA-L
SMILES
[Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O
LogP
-1 at · -1 at 20℃
CAS データベース
7775 · 7775-27-1(CAS DataBase Reference)
EPAの化学物質情報
Sodium persulfate (7775-27-1)
Absorption
309 nm · cut-off at 309nm in H2O at 1M

化学的性質

化学的特性White, crystalline powder. Soluble in water; decomposed by alcohol; decomposes in moist air.

Not combustible but enhances combustion of other substances. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion on contact with combustible substances or reducing agents.

Health Hazards · 2 件

Excerpt from ERG Guide 140 [Oxidizers]:

· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.

Hazards Summary · 1 件

Danger of sensitization of airways and skin; [MAK] Frequent skin rashes are reported in workers exposed to persulfates (S2O8). Rats inhaling 4-20 mg/m3 of ammonium persulfate 23.5 hours/day for 7 days show signs of lung inflammation and loss of body weight. The TLV is proposed to reduce irritation of skin, throat, and respiratory tract. [ACGIH] A skin, eye, and respiratory tract irritant; May cause skin sensitization, dermatitis, and asthma after prolonged contact; [ICSC] An irritant; May cause skin and respiratory sensitization after prolonged contact; [MSDSonline] See Ammonium persulfate and Potassium persulfate.

DOT ID and Guide1505 140
Reactive GroupOxidizing Agents, Strong
UN ClassificationUN Hazard Class: 5.1; UN Pack Group: III
EPA Safer ChemicalChemical: Sodium peroxydisulfate
Reactivity AlertsStrong Oxidizing Agent
Reactivity Profile · 1 件

SODIUM PERSULFATE is a strong oxidizing agent. Reacts with many combustible materials and reducing agents, often vigorously enough to start fires or cause explosions [Handling Chemicals Safely 1980 p. 855]. Decomposes gradually under ordinary conditions decomposition is promoted by moisture and heat [Merck]. Decomposed by alcohol and silver ions [Merck].

安全と保護具

Fire Fighting · 2 件

Excerpt from ERG Guide 140 [Oxidizers]:

In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water.

First Aid Measures · 4 件

Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Give one or two glasses of water to drink. Refer for medical attention .

Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Keep combustibles (wood, paper, oil, etc.) away from spilled material.

First Aid · 2 件

Excerpt from ERG Guide 140 [Oxidizers]:

General First Aid:

Safe StorageWell closed. Separated from combustible substances, reducing agents, strong bases and powdered metals.
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 140 [Oxidizers]:
Spillage Disposal · 1 件

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Carefully collect remainder. Then wash away with plenty of water. Do NOT absorb in saw-dust or other combustible absorbents.

Isolation and Evacuation · 2 件

Excerpt from ERG Guide 140 [Oxidizers]:

Immediate precautionary measure

Eye PreventionWear safety goggles or eye protection in combination with breathing protection if powder.
Fire PreventionNO contact with combustible substances.
Inhalation RiskEvaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

毒性情報

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol and by ingestion.
Toxicity Summary · 2 件

The CIR Expert Panel concluded that Ammonium, Potassium, and Sodium Persulfate are safe as used as oxidizing agents in hair colorants and hair lighteners designed for brief discontinuous use followed by thorough rinsing from the hair and skin. The Panel also concluded that the available data are insufficient for determining the safety of these persulfates in leave-on products and dentifrices.

Safe for use in cosmetics, with qualifications

Signs and Symptoms · 4 件

Cough. Laboured breathing. Sore throat. Wheezing.

Redness. Pain.

Redness. Pain.

Diarrhoea. Nausea. Sore throat. Vomiting.

Toxicity DataLC50 (rat) > 5,100 mg/m3/4h

安全データ

wgk
1
tsca
TSCA listed
rtecs
SE0525000
ridadr
UN 1505
毒性
MLD in rabbits (mg/kg): 178 i.v. (DaVal)
PRTR法
1-395
hs_code
2833 40 00
risk_code
8-22-42/43-36/37/38
安衛法
57,57-2
hazard_code
O,Xn
safety_code
22-36/37-45-36/37/39-26-17
hazard_class
5.1
packing_group
III
Hazard Classifications
Acute Tox. 4 OralOx. Sol. 3Resp. Sens. 1Skin Irrit. 2Skin Sens. 1STOT SE 3
ストレージクラス
5.1B - Oxidizing hazardous materials
危険度評価（NFPA 704基準/消防庁データ）
反応[黄]=0

上流原料

ペルオキソ二硫酸アンモニウム水酸化ナトリウム

下流製品

2-(ブロモメチル)安息香酸Maleic acid-allyl alcohol copolymer