Acrylic Acid → Acrylic acid maleic acid

HRID 47191

反応式

HRID 47191 の反応式
[C:1]([OH:8])(=[O:7])/[CH:2]=[CH:3]\[C:4]([OH:6])=[O:5].[OH-].[Na+].C(O)(=O)C=C.S(OOS([O-])(=O)=O)([O-])(=O)=O.[Na+].[Na+]>O>[C:4]([OH:6])(=[O:5])[CH:3]=[CH2:2].[C:1]([OH:8])(=[O:7])/[CH:2]=[CH:3]\[C:4]([OH:6])=[O:5]

参加物

6

反応物 4

HCID 6581Acrylic AcidHCID 14798Sodium HydroxideHCID 62655Sodium PersulfateHCID 444266Maleic Acid

生成物 1

HCID 86584291Acrylic acid maleic acid

試薬・触媒・溶媒 1

HCID 962Water溶媒3 回

反応条件

温度
95 °C

実験手順

11 g maleic acid was dissolved in 200 g deionized water, and this solution was adjusted to pH 3.85 with 48% aqueous sodium hydroxide. The mixture was heated to 95° C. and kept at 95 to 98° C. in nitrogen atmosphere, and 64 g acrylic acid dissolved in 16 g deionized water, and 4.7 g sodium persulfate dissolved in 50 g deionized water, were separately added dropwise thereto over the period of 2 hours. Thereafter, the reaction solution was kept at 98° C., stirred for 6 hours, and retuned to room temperature to give an aqueous solution of poly(acrylic acid/maleic acid). As a result of measurement of the resulting dispersant by GPC, the weight average molecular weight was 87,000 (determined using polyethylene glycol standards). The conditions for GPC measurement were the same as in Synthesis Example 1.

後処理

  1. customkept at 95 to 98° C. in nitrogen
  2. dissolutiondissolved in 16 g
  3. dissolutiondissolved in 50 g
  4. additionwere separately added dropwise
  5. customover the period of 2 hours
  6. customwas kept at 98° C.
  7. customretuned to room temperature

出典と根拠

ORDレコード
ord-f923d52a2d9f45b3bc38ae9148bf9bca
出典データセット
uspto-grants-2004_03
特許番号
US06699831B2

関連ノート

読み込み中…