D-Arabinose (HCID 66308)

名称と識別子

優先名称: D-Arabinose
IUPAC: (2S,3R,4R)-2,3,4,5-tetrahydroxypentanal
現地名: D-(-)-アラビノース
英語名: D-(-)-Arabinose
分子式: C5H10O5
分子量: 150.13

名称と別名

D-arabinose10323-20-3Arabinose, D-F0W6ETZ4E5DTXSID70858954RefChem:916097GlyTouCan:G16391NRDTXCID6021610CHEBI:17108233-708-5G16391NRD-(-)-Arabinose

名称をさらに表示

D-(-)-アラビノース(2S,3R,4R)-2,3,4,5-テトラヒドロキシペンタナール(-)-D-アラビノースd-アラビノースD(-)‐アラビノースアラビノース, D-(-)-D-(−)-アラビノースD-(-)-アラビノース, 99%DGumsugarPentopyranoseD-ARADPectinoseDPectinsugarD-Arabinose 99%D-(-)-ABABINOSED-Arabinose ,98%D(-)-ArabinoseGr

(2S,3R,4R)-2,3,4,5-tetrahydroxypentanal147-81-9(-)-ArabinoseArabinose,daldehydo-D-arabinoseMFCD00135608DTXSID8041610beta-D-(-)-Arabinose

データベース識別子

CAS: 10323-20-3、147-81-9
PubChem CID: 66308
ChEMBL: CHEMBL1222249、CHEMBL500808
ChEBI: CHEBI:46983
UNII: 509X20752R、F0W6ETZ4E5
EC Number: 205-699-8、233-708-5
Nikkaji: J15.056H

物性

構造計算による物性

XLogP: -2.3
極性表面積: 98 Å²
水素結合供与体数: 4
水素結合受容体数: 5
回転可能結合数: 4
重原子数: 10
形式電荷: 0
複雑度: 104

実験および物理化学的性質

Physical DescriptionWhite powder; [Sigma-Aldrich MSDS]

Collision Cross Section143.27 Å² [M+Na]+ [CCS Type: DT; Method: stepped-field]

物理化学的性質

融点: 156 · 156-160 °C
沸点: 191.65 °C · 191.65°C (rough estimate)
比重(密度): 1.1897 · 1.1897 (rough estimate)
屈折率: -104 ° · -104 ° (C=10, H2O)
貯蔵温度: -20 °C · Inert atmosphere,Store in freezer, under -20°C
溶解性: 21.55 mg/mL · insoluble in EtOH; >21.55 mg/mL in DMSO;
外見: 個体
酸解離定数(Pka): 1 · pK1: 12.34 (25°C)
色: 白い粉
臭い (Odor): 無臭
水溶解度: 水に溶ける。
BRN: 1723079 · 1723079
化粧品成分の機能: スキンコンディショニング保湿剤
InChI: 1S/C5H10O5/c6-2-1-10-5(9)4(8)3(2)7/h2-9H,1H2/t2-,3-,4+,5/m1/s1
InChIKey: SRBFZHDQGSBBOR-ZRMNMSDTSA-N
SMILES: O[C@@H]1COC(O)[C@@H](O)[C@@H]1O
LogP: -2.812 · -2.812 (est)
CAS データベース: 10323 · 10323-20-3(CAS DataBase Reference)
NISTの化学物質情報: D-Arabinose(10323-20-3)
EPAの化学物質情報: D-Arabinose (10323-20-3)

化学的性質

化学的特性white crystalline compound

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 100% (5 of 5) of all reports.

Not Classified；Reported as not meeting GHS hazard criteria by 5 of 5 companies. For more detailed information, please visit ECHA C&L website.

Aggregated GHS information provided per 5 reports by companies from 1 notifications to the ECHA C&L Inventory.；Reported as not meeting GHS hazard criteria per 5 of 5 reports by companies.；There are 0 notifications provided by 0 of 5 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

This chemical does not meet GHS hazard criteria for 66.7% (2 of 3) of all reports.

Warning

危険有害性情報

Regulatory Information · 3 件

Chemical: Arabinose

Chemical: D-Arabinose

D-Arabinose: Does not have an individual approval but may be used under an appropriate group standard

Other Safety Information · 2 件

IMAP assessments - D-Arabinose: Environment tier I assessment；IMAP assessments - D-Arabinose: Human health tier I assessment

IMAP assessments - Arabinose: Environment tier I assessment；IMAP assessments - Arabinose: Human health tier I assessment

Hazards SummaryMay cause irritation; [Sigma-Aldrich MSDS]

Hazard Classes and Categories · 2 件

Not Classified

Skin Irrit. 2 (33.3%)；Eye Irrit. 2A (33.3%)；STOT SE 3 (33.3%)

法規制情報

Regulatory Information · 3 件

Chemical: Arabinose

Chemical: D-Arabinose

D-Arabinose: Does not have an individual approval but may be used under an appropriate group standard

安全データ

F: 3-10
wgk: 3
tsca: TSCA listed
hs_code: 29400000
risk_code: 20/21/22-36/37/38
化審法: (2)-2470
hazard_code: Xn
safety_code: 26-36-24/25
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

UsesArabinose is found in plants (usually as complex polysaccharides) and in mycobacteria; Used in culture media for some bacteria; [Merck Index]

General Manufacturing Information · 2 件

Arabinose: INACTIVE

D-Arabinose: ACTIVE

応用分野

解説D-アラビノースは，Aloebarbadensis(ユリ科)中にある配糖体の成分，結核菌やライ菌の多糖類の成分として存在する．D-グルコースからD-グルコン酸を経て容易に得られる．

使用Isotope labelled analogue of D-Arabinose (A764175), an inhibitor of the enzyme glucose dehydrogenase.

調製方法 · 1 件

純化方法Crystallise D-(-)-arabinose three times from EtOH, dry it in vacuo at 60o for 24hours and store it in a vacuum desiccator. It also crystallises from a mixture of H2O/MeOH/EtOH with m 158-160o, or H2O with m 160-161o. [Whistler & Schweiger J Am Chem Soc 81 5190 1959, Fletcher et al. J Am Chem Soc 72 4546 1950, Beilstein 1 IV 4215, see Angyal Adv Carbohydrate Chem Biochem 42 15 1984 for ratio of anomers in solution.]

上流・下流製品情報

上流原料

Cation exchange resin,strong acidic styrene グルコン酸カルシウム一水和物 D(－)-アラビノース二酢酸バリウム Anion exchange resin,strong basic quarternary ammoniumⅠ オキシドール FERROUS GLUCONATE BP/USP しゅう酸カルシウムメタノール Syrup, NF D-エリトロース

下流製品

D-グルカミン (2R,3R,3aS,9aR)-2,3,3a,9a-テトラヒドロ-6-アミノ-3-ヒドロキシ-4aH-フロ[2',3':4,5]オキサゾロ[3,2-a]ピリミジン-2-メタノールトレオース D-アラビノン酸1,4-ラクトンぎ酸

サプライヤー50 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]

北京华美互利生物化工010-56205725 · [email protected]

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衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

D-(-)-アラビノース

基本情報