(トリクロロメチル)ホスホン酸ジエチル

Diethyl (trichloromethyl)phosphonate

HCID 70085CAS 866-23-9
部分構造検索類似構造を探す

基本情報

標準SMILES
CCOP(=O)(OCC)C(Cl)(Cl)Cl
InChIKey
RVAQSYWDOSHWGP-UHFFFAOYSA-N
分子式
C5.H10.Cl3.O3.P
平均分子量
255.5 g/mol
単同位体質量
253.94331385

名称と識別子

優先名称
Diethyl (trichloromethyl)phosphonate
IUPAC
1-[ethoxy(trichloromethyl)phosphoryl]oxyethane
現地名
(トリクロロメチル)ホスホン酸ジエチル
英語名
Diethyl (trichloromethyl)phosphonate
分子式
C5H10Cl3O3P
分子量
255.46

名称と別名

Diethyl (trichloromethyl)phosphonateRefChem:587041622-785-4866-23-9Diethyl trichloromethylphosphonateDiethyltrichloromethylphosphonate1-[ethoxy(trichloromethyl)phosphoryl]oxyethaneRo 3-0658MFCD00013666Phosphonic acid, trichloromethyl-, diethyl esterPhosphonic acid, (trichloromethyl)-, diethyl esterAI3-18556
名称をさらに表示
(トリクロロメチル)ホスホン酸ジエチルトリクロロメチルホスホン酸ジエチルジエチル(トリクロロメチル)ホスホナートRo-30658TIMTEC-BB SBB008195diethyl trichloromethanephosphonateTrichloromethylphosphonic acid diethylDiethyl (trichloromethyl)phosphonate 97%(Trichloromethyl)phosphonic acid diethylDiethyl (Trichloromethyl)phosphonate >trichloromethyl-phosphonicacidiethylesterDIETHYL (TRICHLOROMETHYL)PHOSPHONATE, 97 %
WLN: GXGGPO&O2&O2(Trichloromethyl)phosphonic Acid Diethyl EsterNSC-46567CS-0151420EN300-7867510NSC 46567BRN 1210640C5H10Cl3O3P

データベース識別子

CAS
866-23-9
PubChem CID
70085
DTXSID
DTXSID50235688
UNII
LKC8DWP2F4
EC Number
622-785-4
Nikkaji
J7.147A

物性

構造計算による物性

XLogP
2.2
極性表面積
35.5 Ų
水素結合供与体数
0
水素結合受容体数
3
回転可能結合数
4
重原子数
12

実験および物理化学的性質

SpringerMaterials PropertiesViscosity
Density1.362 @25 °C

物理化学的性質

沸点
130 · 130-131 °C/14 mmHg (lit.)
比重(密度)
1.362 g/mL · 1.362 g/mL at 25 °C (lit.)
屈折率
20 · n20/D 1.463(lit.)
闪点
230 °F · >230 °F
貯蔵温度
2 · 2-8°C
外見
液体

化学的性質

化学的特性Colorless to Almost colorless clear liquid.

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H302 (11.1%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesAcute Tox. 4 (11.1%)

安全と保護具

Protective Action Criteria (PAC) · 3 件

2.4 [mg/m3]

26 [mg/m3]

160 [mg/m3]

安全データ

F
9-21
wgk
3
rtecs
TA0988000
ridadr
UN3278
hs_code
29319000
risk_code
36/37/38-22

化学と産業

応用分野 · 2 件

使用Diethyl (trichloromethyl)phosphonate may be used in the synthesis of chlorovinyl phosphonates via reaction with aldehydes and ketones.

一般的な説明Addition reaction of diethyl (trichloromethyl)phosphonate to olefins by non-chain catalytic reactions catalyzed by copper amine complexes has been reported. Irradiation of diethyl (trichloromethyl)phosphonate in MeCN is reported to afford corresponding monoesters and olefins, via photochemical type II elimination reaction.

調製方法 · 1 件

製造方法Diethyl trichloromethylphosphonate was also obtained from diethyltrimethylsilyl phosphite in 60 % yield, and from benzyldiethyl phosphite in the presence of dibenzoyl peroxide and an ultraviolet source in a radical induced reaction in 87 % yield (compared to 26 % without the dibenzoyl peroxide).

上流・下流製品情報

サプライヤー48 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
南京世洲生物科技有限公司025-85560043 15850508050 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

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