4,4'-ジアミノジフェニルメタン

4,4-Diaminodiphenylmethane

HCID 7577CAS 101-77-9

基本情報

標準SMILES
Nc1ccc(Cc2ccc(N)cc2)cc1
InChIKey
YBRVSVVVWCFQMG-UHFFFAOYSA-N
分子式
C13H14N2
平均分子量
198.26 g/mol
単同位体質量
198.11569846

名称と識別子

優先名称
4,4-Diaminodiphenylmethane
IUPAC
4-[(4-aminophenyl)methyl]aniline
現地名
4,4'-ジアミノジフェニルメタン
英語名
4,4'-Methylenedianiline
分子式
C13H14N2
分子量
198.26

名称と別名

4,4'-Methylenedianiline101-77-94,4'-DIAMINODIPHENYLMETHANEDadpmMethylenedianiline4-[(4-aminophenyl)methyl]anilineBis(4-aminophenyl)methaneDianilinemethaneDianilinomethanep,p'-MethylenedianilineEpicure DDMEpikure DDM
名称をさらに表示
4,4'-ジアミノジフェニルメタンジアニリノメタン4,4'-メチレンビス(ベンゼンアミン)メチレンビス(p-フェニレン)ジアミン4,4'-メチレンビス(アニリン)4,4'-メチレンビスベンゼンアミン4,4'-メチレンビスアニリン4,4'-メチレンジアニリントノックスジ(4-アミノフェニル)メタンビス(4-アミノフェニル)メタンN,N'-メチレンビスアニリン4,4'-メチレンジ(アニリン)N,N'-ジフェニルメタンジアミン6,6'-メチレンジサリチル酸[メチレンビス(p-フェニレン)]ジアミン[4,4'-メチレンビスアニリン]4,4'-メチレンジサリチル酸4,4'-メチレンビス[ベンゼンアミン]4,4’-ジアミノジフェニルメタンDiaminodiphenylmethane4,4-METHYLENEDIANILINEMDA-100Bis-(4-aMinoRubber antioxidant
Curithane4-(4-Aminobenzyl)anilineBenzenamine, 4,4'-methylenebis-Jeffamine AP-20p,p'-DiaminodiphenylmethaneSumicure M4,4'-DiphenylmethanediamineAncamine TL

データベース識別子

CAS
101-77-9、1219795-26-2
PubChem CID
7577
DTXSID
DTXSID6022422
ChEMBL
CHEMBL85728
ChEBI
CHEBI:32506
UNII
GG5LL7OBZC
EC Number
202-974-4、663-410-4
Nikkaji
J4.995F

物性

構造計算による物性

XLogP
1.6
極性表面積
52 Ų
水素結合供与体数
2
水素結合受容体数
2
回転可能結合数
2
重原子数
15

物理化学的性質

融点
89 · 89-91 °C(lit.)
沸点
242 °C2 · 242 °C2 mm Hg(lit.)
比重(密度)
1.15 · 1.15
蒸気圧
0 Pa · 0Pa at 25℃
屈折率
1.5014 · 1.5014 (estimate)
闪点
430 °F · 430 °F
化学的性質 · 1 件

化学的特性4,4-Diaminodiphenylmethane is a pale yellow crystalline solid (turns light brown on contact with air) with a faint amine-like odor that is unstable in the presence of light or air and emits toxic fumes of aniline and nitrogen oxides when heated to decomposition. 4,4'-Methylenedianiline is primarily used in industry as a chemical intermediate in the production of 4,4-methylenedianiline diisocyanates and polyisocyanates, but is also used as a cross-linking agent for the determination of tungsten and sulfates, and as a corrosion inhibitor. Exposure to this substance irritates the skin and eyes and causes liver damage. 4,4'-Methylenedianiline is reasonably anticipated to be a human carcinogen. (NCI05)

安全と法規制

安全データ

wgk
3
tsca
TSCA listed
rtecs
BY5425000
ridadr
UN 2651
毒性
LD50 oral in rabbit: 620mg/kg
PRTR法
第一種指定化学物質

化学と産業

応用分野 · 5 件

用途染料、樹脂硬化剤

用途4,4'-メチレンビス(フェニルイソシアナート)(MDI)?ポリメリックMDIの合成原料、エポキシ樹脂?ポリウレタン樹脂の硬化剤、染料中間体、エポキシ樹脂硬化剤

説明4,4'-Methylenedianiline is an industrial chemical that is not known to occur naturally. It is also commonly known as diaminodiphenylmethane or MDA. It occurs as a colorless to pale yellow solid and has a faint odor. 4,4'-Methylenedianiline is used mainly for making polyurethane foams, which have a variety of uses, such as insulating materials in mailing containers. It is also used for making coating materials, glues, Spandex fiber, dyes, and rubber. 4,4'-Methylenedianiline is also a by-product of azo dyes. It is also possibly formed by hydrolysis of diphenylmethane-4A'-diisocyanate.

使用4,4'-methylenedianiline be used as organic intermediates. Mainly used for the synthesis of polyimide and as curing agent of epoxy resin.

一般的な説明A tan flake or lump solid with a faint fishlike odor. May be toxic by inhalation or ingestion, and may be irritating to skin. Insoluble in water.

調製方法

純化方法Crystallise the amine from water, 95% EtOH or *benzene. [Beilstein 13 IV 390.]

サプライヤー50 社

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Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
Hebei Yanxi Chemical Co., Ltd.+86-17531190177 · [email protected]
補足説明 · 1 件

定義ChEBI: 4,4'-Methylenedianiline is an aromatic amine that is diphenylmethane substituted at the 4-position of each benzene ring by an amino group. It is primarily used in industry as a chemical intermediate in the production of 4,4-methylenedianiline diisocyanates and polyisocyanates.

関連反応

45 件

関連ノート

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