2,5-ジメチル-2,5-ジ(ベンゾイルペルオキシ)ヘキサン
2,5-Dimethyl-2,5-DI-(benzoylperoxy)hexane
基本情報
- CAS
2618-77-1- 標準SMILES
CC(C)(CCC(C)(C)OOC(=O)c1ccccc1)OOC(=O)c1ccccc1- InChIKey
RIPYNJLMMFGZSX-UHFFFAOYSA-N- 分子式
- C22H26O6
- 平均分子量
- 386.4 g/mol
- 単同位体質量
- 386.17293855
概要
This solid peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported as a mixture, with an inert solid.
名称と識別子
- 優先名称
- 2,5-Dimethyl-2,5-DI-(benzoylperoxy)hexane
- IUPAC
- (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate
- 現地名
- 2,5-ジメチル-2,5-ジ(ベンゾイルペルオキシ)ヘキサン
- 英語名
- 2,5-Dimethyl-2,5-di(benzoylperoxy)hexane
- 分子式
- C22H26O6
- 分子量
- 386.44
名称と別名
2,5-dimethyl-2,5-di(benzoylperoxy)hexaneEINECS 220-050-9Benzenecarboperoxoic acid, 1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl) esterDTXSID5062556Benzenecarboperoxoic acid, 1,1,4,4-tetramethyl-1,4-butanediyl ester2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE, (TECHNICALLY PURE)2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE, [TECHNICALLY PURE]KAYAESTER AB2,5-dimethyl-2,5-di-(benzoylperoxy)hexaneRefChem:444518PERHEXA 25ZLUPERSOL 118
名称をさらに表示
2,5-ジメチル-2,5-ビス(ベンゾイルペルオキシ)ヘキサンビス(過安息香酸)2,5-ジメチルヘキサン-2,5-ジイルビス(ベンゼンカルボペルオキソ酸)2,5-ジメチル-2,5-ヘキサンジイル2,5-ジメチル-2,5-ジ(ベンゾイルペルオキシ)ヘキサン2，5ジメチル2，5ビス（ベンゾイルパ-オキシ）ヘキサン2,5-ジメチルー2,5-ビス(ベンゾイルパーオキシ)ヘキサン2,5-ジメチル-2,5-ジ(ベンゾイルパーオキシ)ヘキサン5-(ベンゾイルペルオキシ)-2,5-ジメチルヘキサン-2-イル ベンゼンカルボペルオキソアートL-118VAROX 118VAROX 230-XLVAROX DCP-40CVAROX DCP-40KE2,5-Dimethylhexane-2,5-diperbenzoate2,5-Dimethylhexan-2,5-diyldiperbenzoat
物性
構造計算による物性
- XLogP
- 5.4
- 極性表面積
- 71.1 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 6
- 回転可能結合数
- 11
- 重原子数
- 28
- 形式電荷
- 0
- 複雑度
- 455
実験および物理化学的性質
Physical DescriptionThis solid peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported as a mixture, with an inert solid.
物理化学的性質
- 沸点
- 529.9 · 529.9±33.0 °C(Predicted)
- 比重(密度)
- 1.143 · 1.143±0.06 g/cm3(Predicted)
- EPAの化学物質情報
- 1 · Benzenecarboperoxoic acid, 1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl) ester (2618-77-1)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Danger
H241: Heating may cause a fire or explosion [Danger Self-reactive substances and mixtures; Organic peroxides]
P210, P234, P235, P240, P280, P370+P380+P375[+P378], P403, P410, P411, P420, and P501 (click each P-code to see the statement)
危険有害性情報
Regulatory InformationChemical: Benzenecarboperoxoic acid, 1,1,4,4-tetramethyl-1,4-butanediyl ester
DOT LabelOrganic Peroxide Explosive
Fire HazardsExcerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Health HazardsExcerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Reactive GroupPeroxides, Organic
Reactivity AlertsExplosive
Reactivity Profile
Peroxides, such as 2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE, are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness. Danger of explosion when dry. May explode from heat or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames.
化学と産業
用途と製造
General Manufacturing InformationBenzenecarboperoxoic acid, 1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl) ester: ACTIVE
応用分野
用途ラジカル開始剤、樹脂硬化剤,架橋剤
一般的な説明2,5-DIMETHYL-2,5-DI(BENZOYLPEROXY)HEXANE is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. 2,5-DIMETHYL-2,5-DI(BENZOYLPEROXY)HEXANE is generally stored or transported as a mixture, with an inert solid.
関連反応
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化合物ノート
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