2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane → tert-Butyl peroxybenzoate

HRID 1654593

反応式

HRID 1654593 の反応式
C(OO[C:7]1(OOC(C)(C)C)[CH2:12][CH:11](C)[CH2:10][C:9]([CH3:15])(C)[CH2:8]1)(C)(C)C.[C:22]([O:26][O:27]C1(OOC(C)(C)C)CCCCC1)([CH3:25])([CH3:24])[CH3:23].C([O:44]OC(C(C)(C)CC(C)C)C([O-])=O)(C)(C)C.C(=O)([O-])OC(OOC(C)(C)C)(C)C.CC(OOC(=O)C1C=CC=CC=1)(CCC(C)(OOC(=O)C1C=CC=CC=1)C)C.C(OOOC(C)(C)C)(=O)C1C=CC=CC=1.C(OOC(C1C=CC=CC=1)(C)C)(C1C=CC=CC=1)(C)C.CC(OOC(C)(C)C)(CCC(C)(OOC(C)(C)C)C)C.C(OOC(CC)(CCCC)C([O-])=O)(C)(C)C.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>>[C:22]([O:26][O:27][C:15](=[O:44])[C:9]1[CH:8]=[CH:7][CH:12]=[CH:11][CH:10]=1)([CH3:25])([CH3:24])[CH3:23]

参加物

11

反応物 10

HCID 65452,5-Dimethyl-2,5-di-(tert-butylperoxy)hexaneHCID 6641Dicumyl peroxideHCID 7187Benzoyl PeroxideHCID 757962,5-Dimethyl-2,5-DI-(benzoylperoxy)hexaneHCID 763591,1-Bis(tert-butylperoxy)cyclohexaneHCID 930381,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexaneHCID 21744378t-Butylperoxy benzoateHCID 21753036HCID 21753036、化合物HCID 22065482t-Butylperoxy(2-ethylhexanoate)HCID 86748635HCID 86748635、化合物

生成物 1

HCID 11966tert-Butyl peroxybenzoate

実験手順

As the polymerization initiator, organic peroxides such as 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, 1,1-bis(t-butylperoxy)cyclohexane, t-butylperoxy-3,3,5-trimethylhexanoate, t-butylperoxyisopropyl carbonate, 2,5-dimethyl-2,5-di(benzoylperoxy)hexane, t-butylperoxy benzoate, dicumylperoxide, 2,5-dimethyl-2,5-di(t-butyl peroxy)hexane, t-butylperoxy(2-ethylhexanoate), di-t-butyl hydroperoxide, t-butylperoctoate, benzoylperoxide, etc. are used. In order to obtain a superior surface quality in a usual molding time, t-butyl-peroxybenzoate alone or in an admixture with another compound is preferably used.

出典と根拠

ORDレコード
ord-b21e0bf705aa4fbc98b3111d4a5a1a59
出典データセット
uspto-grants-1995_04
特許番号
US05408013

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