6-Bromo-1-hexene (HCID 75906)

名称と識別子

優先名称: 6-Bromo-1-hexene
IUPAC: 6-bromohex-1-ene
現地名: 6-ブロモ-1-ヘキセン
英語名: 6-Bromo-1-hexene
分子式: C6H11Br
分子量: 163.06

名称と別名

6-Bromo-1-hexene2695-47-86-Bromohex-1-ene5-Hexenyl bromide1-Hexene, 6-bromo-1-Bromo-5-hexene6-Bromohexene6-bromo-hex-1-ene6-bromo-hexeneMFCD00000269EINECS 220-267-91-Bromo-5-hexene; 5-Hexen-1-yl Bromide; 5-Hexenyl Bromide; 6-Bromo-1-hexene

名称をさらに表示

6-ブロモ-1-ヘキセン5-ヘキセニルブロミド6‐ブロモ‐1‐ヘキセン6-ブロモヘキス-1-エン6-ブロモヘキサ-1-エンBromohexene-BroMo-1-hexene1-Hexene,6-bromo-Bromo-1-hexene,6-

l-bromo-5-hexene6-bromo-1-hexen1-bromohex-5-enebromo(6-)-1-hexene5-Hexen-1-yl bromideAB1011877Z28AT4BT8S6-Bromo-1-hexene, 95%

データベース識別子

CAS: 2695-47-8
PubChem CID: 75906
DTXSID: DTXSID6062595
UNII: Z28AT4BT8S
EC Number: 220-267-9
Nikkaji: J97.486B

物性

構造計算による物性

XLogP: 2.8
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 4
重原子数: 7
形式電荷: 0
複雑度: 41.4

実験および物理化学的性質

Chemical ClassesOther Classes -> Halogenated Aliphatics, Unsaturated

SpringerMaterials PropertiesDensity

Physical DescriptionColorless liquid; [Alfa Aesar MSDS]

物理化学的性質

融点: -102.35 °C · -102.35°C (estimate)
沸点: 47 · 47-51 °C/16 mmHg (lit.)
比重(密度): 1.22 g/mL · 1.22 g/mL at 25 °C (lit.)
屈折率: 20 · n20/D 1.4652(lit.)
闪点: 126 °F · 126 °F
貯蔵温度: -20 °C · Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
溶解性: Chloroform (Slightly), Methanol (Slightly)
外見: 液体
色: やや黄色く澄んでいる
比重: 1.217 · 1.217
水溶解度: 水には混和しません。
BRN: 506203 · 506203
安定性: 安定。強酸化剤、強塩基とは相容れない。可燃性。
InChI: 1S/C6H11Br/c1-2-3-4-5-6-7/h2H,1,3-6H2
InChIKey: RIMXEJYJXDBLIE-UHFFFAOYSA-N
SMILES: BrCCCCC=C
CAS データベース: 2695 · 2695-47-8(CAS DataBase Reference)
NISTの化学物質情報: 1 · 1-Hexene, 6-bromo-(2695-47-8)
EPAの化学物質情報: 1 · 1-Hexene, 6-bromo- (2695-47-8)

化学的性質

化学的特性colourless liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 53 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards SummaryA skin and strong eye irritant; [Alfa Aesar MSDS] See Allyl iodide and Allyl bromide. See 3,4-Dichloro-1-butene and 3-Chloro-2-methyl-1-propene.

Hazard Classes and CategoriesFlam. Liq. 3 (100%)

安全データ

F: 8
wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
hs_code: 29039990
risk_code: 10-36/37/38-61
化審法: (2)-67
消防法: 危-4-2-III
hazard_code: Xi,F,T
hazard_note: Flammable/Irritant
safety_code: 26-36-37/39-16-45-53
hazard_class: 3.2
packing_group: III
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Repr. 1BSkin Irrit. 2STOT SE 3
ストレージクラス: 3 - Flammable liquids

化学と産業

用途と製造

General Manufacturing Information1-Hexene, 6-bromo-: ACTIVE

応用分野 · 2 件

用途有機合成原料。

一般的な説明Reaction of 6-bromo-1-hexene with Mg to form Grignard compounds has been investigated. The thermal chemistry of 6-bromo-1-hexene on Ni (100) surface has been studied under ultrahigh vacuum conditions by X-ray photoelectron spectroscopy and temperature-programmed desorption.