1,1-Bis(tert-butylperoxy)cyclohexane (HCID 76359)

概要

Organic solvent solution, added to lessen explosion hazard.

名称と識別子

優先名称: 1,1-Bis(tert-butylperoxy)cyclohexane
IUPAC: 1,1-bis(tert-butylperoxy)cyclohexane
現地名: 1,1-ビス(1,1-ジメチルエチルペルオキシ)シクロヘキサン
英語名: 1,1-Di(tert-butylperoxy)cyclohexane
分子式: C14H28O4
分子量: 260.37

名称と別名

1,1-Bis(tert-butylperoxy)cyclohexane3006-86-8Cyclohexylidenebis(tert-butyl) peroxideUNII-JK62J3E3Q4JK62J3E3Q4EINECS 221-111-2PERHEXA CSLuperox 331M80Peroxide, 1,1'-cyclohexylidenebis(2-(1,1-dimethylethyl)EC 221-111-2PERHEXA C 40PERHEXA C 75

名称をさらに表示

1,1-ビス(tert-ブチルペルオキシ)シクロヘキサン1,1-ビス(1,1-ジメチルエチルペルオキシ)シクロヘキサン1,1-ビス(tert-ブチルジオキシ)シクロヘキサンペルヘキサC1,1-ジ(TERT-ブチルペルオキシ)シクロヘキサン,50%ミネラルオイル溶液ジｔｅｒｔブチル＝シクロヘキシリデン＝ジペルオキシド1，1-ビス（t-ブチルパーオキシ）シクロヘキサン1,1-ビス(ターシャリ-ブチルパーオキシ)シクロヘキサン1,1‐ジ(TERT‐ブチルペルオキシ)シクロヘキサン,50%ミネラルオイル溶液LUPEROX® 331M80、1,1-ビス(TERT-ブチルペルオキシ)シクロヘキサン溶液1,1-ジ(tert-ブチルペルオキシ)シクロヘキサン1,1-bis(T-butylperoxy)cyclohexaneDP275BPerhexa-CChaloxyd PTrigonox 22Lupersol 331TRIGONOX(R) 22Luperox? 331P80

PEROXAN PK 122WTRIGONOX 22C50TRIGONOX 22E50TRIGONOX 22E70LUPEROX 331DTXSID4044907TX 22E50Cyclohexylidenebis[tert-butyl] peroxide

データベース識別子

CAS: 3006-86-8
PubChem CID: 76359
DTXSID: DTXSID4044907
UNII: JK62J3E3Q4
EC Number: 221-111-2
Nikkaji: J4.394J

物性

構造計算による物性

XLogP: 3.7
極性表面積: 36.9 Å²
水素結合供与体数: 0
水素結合受容体数: 4
回転可能結合数: 6
重原子数: 18
形式電荷: 0
複雑度: 224

実験および物理化学的性質

Physical Description · 3 件

Organic solvent solution, added to lessen explosion hazard.

Particularly heat and contamination sensitive.

CBI; Liquid

物理化学的性質

融点: 65 °C · 65 °C (SADT)
沸点: 52 · 52-54 °C (0.1 mmHg)
比重(密度): 0.891 g/mL · 0.891 g/mL at 25 °C
蒸気圧: 4.88 hPa · 4.88hPa at 25℃
屈折率: 20 · n20/D 1.435
闪点: 155 °F · 155 °F
貯蔵温度: 2 · 2-8°C
外見: 液体
色: クリア
水溶解度: 混和性
InChI: InChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3
InChIKey: HSLFISVKRDQEBY-UHFFFAOYSA-N
SMILES: C1(CCCCC1)(OOC(C)(C)C)OOC(C)(C)C
LogP: 7.2 at · 7.2 at 25℃
CAS データベース: 3006 · 3006-86-8(CAS DataBase Reference)
EPAの化学物質情報: 1 · Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) (3006-86-8)

化学的性質

化学的特性clear liquid

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 1.8% (3 of 170) of reports.

Danger

H242 (74.7%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

P210, P234, P235, P240, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403, P403+P233, P405, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 170 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

危険有害性情報

Regulatory Information · 4 件

Chemical: Peroxide, cyclohexylidenebis[(1,1-dimethylethyl)

Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 15-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5875

Peroxide, cyclohexylidenebis(1,1-dimethylethyl): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

DOT Label · 4 件

Organic Peroxide

Organic Peroxide Explosive

Fire Hazards · 4 件

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Health Hazards · 4 件

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Reactive Group · 4 件

Peroxides, Organic

Reactivity Alerts · 4 件

Strong Oxidizing Agent

Explosive

Reactivity Profile · 4 件

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]

The explosive instability of the lower dialkyl peroxides (e.g.,. dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]

The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the mono functional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]

安全と保護具

Fire Fighting · 4 件

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

First Aid · 4 件

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Nonfire Spill Response · 4 件

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Isolation and Evacuation · 4 件

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

Personal Protective Equipment (PPE) · 4 件

Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

安全データ

wgk: 2
tsca: TSCA listed
ridadr: UN 3103 5.2
hs_code: 29096000
risk_code: 7-62-50/53-36/37/38-61-65-45-51/53
消防法: 危-5-PO-2-II
hazard_code: O,N,T
safety_code: 17-36/37/39-3/7-14A-61-60-45-26-14-53-62
hazard_class: 5.2
packing_group: II
Hazard Classifications: Asp. Tox. 1Carc. 1BEye Irrit. 2Muta. 1BOrg. Perox. CSkin Irrit. 2STOT SE 3
ストレージクラス: 4.1A - Other explosive hazardous materials

化学と産業

用途と製造

U.S. Production2023: 1,000,000 - <2,500,000 lb

Consumer UsesNot Known or Reasonably Ascertainable

Industry UsesCBI

General Manufacturing Information · 2 件

Plastics Material and Resin Manufacturing

Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl): ACTIVE

応用分野

用途ラジカル重合開始剤,不飽和ポリエステル硬化剤

使用Polymerization initiator.

サプライヤー50 社

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]

Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]

湖北鑫杰成化工科技有限公司13554075426 · [email protected]

補足説明

定義1,1-Di (tert-butylperoxy) cyclohexane (DTBPH) is a commercial liquid organic peroxide that is to be in aliphatic hydrocarbon solvent and transported and stored under limited temperature[1].