Allylchlorodimethylsilane (HCID 77646)

名称と識別子

優先名称: Allylchlorodimethylsilane
IUPAC: chloro-dimethyl-prop-2-enylsilane
現地名: アリルクロロジメチルシラン
英語名: Allyldimethylchlorosilane
分子式: C5H11ClSi
分子量: 134.68

名称と別名

Allyldimethylchlorosilane4028-23-3AllylchlorodimethylsilaneSilane, chlorodimethyl-2-propenyl-Silane, chlorodimethyl-2-propen-1-yl-6AL6CP5RFJEINECS 223-706-2DTXSID1063271RefChem:554910Silane, chlorodimethyl2propenylDTXCID8039746Silane, chlorodimethyl2propen1yl

名称をさらに表示

アリルクロロジメチルシランアリルジメチルクロロシラン2-プロペニルクロロジメチルシランアリル(クロロ)ジメチルシランクロロジメチルアリルシランアリルジメチルシリルクロリドクロロアリルジメチルシランジメチルアリルクロロシランジメチルクロロアリルシラン3-(ジメチルクロロシリル)-1-プロペンADMCSDK287DK774admsclAllylchlordimethylsilanLLYLCHLORODIMETHYLSILANEDimethylallylchlorosilaneChlorodimethylallylsilaneChloroallyldimethylsilane

223-706-2Allyl(chloro)dimethylsilanechloro-dimethyl-prop-2-enylsilaneMFCD00000506allyl-chloro-dimethyl-silaneS00225Allyldimethylsilyl ChlorideAllylchlorodimethylsilane; chloro-dimethyl-prop-2-enylsilane; ALLYLDIMETHYLCHLOROSILANE; Allyl(chloro)dimethylsilane; Allyldimethylsilyl Chloride;

データベース識別子

CAS: 4028-23-3
PubChem CID: 77646
DTXSID: DTXSID1063271
UNII: 6AL6CP5RFJ
EC Number: 223-706-2
Nikkaji: J217.847H

物性

構造計算による物性

極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 2
重原子数: 7
形式電荷: 0
複雑度: 68

実験および物理化学的性質

Physical DescriptionColorless liquid; [Alfa Aesar MSDS]

物理化学的性質

沸点: 111113 °C · 111113°C
比重(密度): 0.922 g/mL25°C · 0.922g/mL25°C
屈折率: 1.427 · 1.427-1.431
闪点: 42 °F · 42 °F
貯蔵温度: 0 · 0-10°C
外見: clear liquid
色: Colorless to Light yellow
比重: 0.922 · 0.922
水溶解度: ほとんどの有機溶媒に可溶。アルコール、アミン、および水と反応します。
BRN: 1737978 · 1737978
InChI: InChI=1S/C5H11ClSi/c1-4-5-7(2,3)6/h4H,1,5H2,2-3H3
InChIKey: KMVZWUQHMJAWSY-UHFFFAOYSA-N
SMILES: [Si](Cl)(C)(C)CC=C
CAS データベース: 4028 · 4028-23-3(CAS DataBase Reference)
EPAの化学物質情報: -2 · Silane, chlorodimethyl-2-propenyl- (4028-23-3)

化学的性質

化学的特性clear colorless to light yellow liquid

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 44 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract; [Alfa Aesar MSDS] See Allyltrichlorosilane.

Hazard Classes and CategoriesFlam. Liq. 2 (100%)；Skin Corr. 1B (100%)

毒性情報

Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

安全データ

wgk: 1
tsca: TSCA listed
ridadr: UN 2985 3/PG 2
hs_code: 29319000
risk_code: 11-34
化審法: (2)-2042
消防法: 危-4-1-II
hazard_code: F,C
safety_code: 16-26-36/37/39-45
hazard_class: 3
packing_group: II
Hazard Classifications: Flam. Liq. 2Skin Corr. 1B
ストレージクラス: 3 - Flammable liquids

化学と産業

用途と製造

General Manufacturing InformationSilane, chlorodimethyl-2-propen-1-yl-: ACTIVE

応用分野 · 1 件

使用Allylchlorodimethylsilane is used in the synthesis of cyclo-1,1,4,4-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene, silylating agent for steroids for analysis by GC-MS. Also used in the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers, O-silylation of phenyl sulfones.