Bis(eta-cyclopentadienyl) iron → HCID 178460910、化合物

HRID 962952

反応式

HRID 962952 の反応式
[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11].[CH2:12]([Si:15]([CH3:18])([CH3:17])[Cl:16])[CH:13]=[CH2:14]>>[Cl:16][Si:15]([CH3:18])([CH3:17])[CH2:12][CH:13]([C-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1)[CH3:14].[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11]

参加物

3

反応物 2

HCID 7611Bis(eta-cyclopentadienyl) ironHCID 77646Allylchlorodimethylsilane

生成物 1

HCID 178460910HCID 178460910、化合物収率 20%

実験手順

In the same apparatus and procedures as EXAMPLE 1 above, 0.30 g(1.61 mmol) of ferrocene was reacted with 0.92 mL(6.3 mmol) of allyldimethylchlorosilane under dry nitrogen atmospheric pressure for 2 hrs. After the addition of the catalyst solution, the reaction mixture was stirred for an additional 2 hrs to complete the alkylation. The solvent was distilled off at atmospheric pressure and the products were then extracted with 20.0 ml. of hexane. The reaction products were distilled under vacuum at 200° C. and at 0.5 torr, and produced 0.1 g of (3-chloro-1,3-dimethyl-3-silabutyl)ferrocene (yield; 20%). The remaining products were vacuum distilled at 300° C. and at 0.5 torr, and 0.55 g of bis(3-chloro-1,3-dimethyl-3-silabutyl)ferrocenes(yield; 38%) was obtained.

後処理

  1. additionAfter the addition of the catalyst solution
  2. distillationThe solvent was distilled off at atmospheric pressure
  3. extractionthe products were then extracted with 20.0 ml
  4. distillationThe reaction products were distilled under vacuum at 200° C. and at 0.5 torr

出典と根拠

ORDレコード
ord-a86a59e552dd4c28b3bf30e9d9778bf0
出典データセット
uspto-grants-1998_06
特許番号
US05760263

関連ノート

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