N,N,N',N',N'',N''-Hexamethylmethanetriamine (HCID 79831)

名称と識別子

優先名称: N,N,N',N',N'',N''-Hexamethylmethanetriamine
IUPAC: N,N,N',N',N",N"-hexamethylmethanetriamine
現地名: トリス(ジメチルアミノ)メタン
英語名: Tris(dimethylamino)methane
分子式: C7H19N3
分子量: 145.25

名称と別名

5762-56-1N,N,N',N',N'',N''-HexamethylmethanetriamineEINECS 227-284-0DTXSID20206284RefChem:822031DTXCID20128775227-284-0Tris(dimethylamino)methane[bis(dimethylamino)methyl]dimethylamineN,N,N',N',N",N"-hexamethylmethanetriamineMFCD00008322N,N,N,N,N,n-Hexamethylmethanetriamine

名称をさらに表示

トリス(ジメチルアミノ)メタンN,N',N''-メチリジントリス(ジメチルアミン)N,N,N',N',N'',N''-ヘキサメチルメタントリアミンN,N,N′,N′,N′′,N′′-ヘキサメチルメタントリアミンN,N′,N′′-メチリジントリス(ジメチルアミン)[ビス(ジメチルアミノ)メチル]ジメチルアミンTris(N,N-dimethylamino)methaneTris(dimethylamino)methane,85%Tris(dimethylamino)methane 97%Tris(dimethylamino) methane, 96%+Tris(diMethylaMino)Methane, 85% 5GRN,N',N''-Methylidynetris(dimethylamine)

Methanetriamine, N,N,N',N',N'',N''-hexamethyl-8T74D2Q5VHtrisdimethylaminomethanetris-dimethylaminomethanetris (dimethylamino)methanetris(dimethylamino) methanetris(dimethylamino)-methanetris-(dimethylamino)methane

データベース識別子

CAS: 5762-56-1
PubChem CID: 79831
DTXSID: DTXSID20206284
ChEMBL: CHEMBL3301703
UNII: 8T74D2Q5VH
EC Number: 227-284-0
Nikkaji: J209.013I

物性

構造計算による物性

XLogP: 0.6
極性表面積: 9.7 Å²
水素結合供与体数: 0
水素結合受容体数: 3
回転可能結合数: 3
重原子数: 10
形式電荷: 0
複雑度: 69.8

物理化学的性質

沸点: 42 · 42-43 °C/12 mmHg (lit.)
比重(密度): 0.838 g/mL · 0.838 g/mL at 20 °C (lit.)
屈折率: 20 · n20/D 1.436(lit.)
闪点: 4 °F · 4 °F
貯蔵温度: 2 · 2-8°C
外見: 液体
酸解離定数(Pka): 6.5 · 6.50±0.38(Predicted)
色: 無色透明～微黄色透明
BRN: 1901162 · 1901162
InChI: InChI=1S/C7H19N3/c1-8(2)7(9(3)4)10(5)6/h7H,1-6H3
InChIKey: MUMVIYLVHVCYGI-UHFFFAOYSA-N
SMILES: C(N(C)C)(N(C)C)N(C)C

化学的性質

化学的特性Clear colorless to slightly yellow liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

安全データ

F: 3-8-10-21
wgk: 3
ridadr: UN 2733 3/PG 2
hs_code: 29212900
risk_code: 11-34
消防法: 危-4-1-II
hazard_code: F,C
hazard_note: Corrosive/Highly Flammable
safety_code: 16-26-36/37/39-45
hazard_class: 3.1
packing_group: II
Hazard Classifications: Flam. Liq. 2Skin Corr. 1B
ストレージクラス: 3 - Flammable liquids

化学と産業

応用分野

使用Tris(dimethylamino)methane was used:to prepare the phosphoramidite derivative of the new nucleoside analogas reagent for the introduction of the dimethylaminoethylidene group in ring-opening (RO) polymerization of lactide

一般的な説明NMR spectra and their temperature-dependence has been reported for tris(dimethylamino)methane. Tris(dimethylamino)methane reacts with crowded α-(o-nitrophenyl) ketone to yield tetrahydroquinoline derivative.

調製方法

純化方法Dry it over KOH and distil it through a Vigreux column (p 11) at water pump vacuum. Store it in the absence of CO2. [Bredereck et al. Chem Ber 101 1885 1968 and Angew Chem, Int Ed Engl 5 132 1966.]