CAS 6737-42-4 1,3-Bis(diphenylphosphino)propane (HCID 81219)

名称と識別子

優先名称: 1,3-Bis(diphenylphosphino)propane
IUPAC: 3-diphenylphosphanylpropyl(diphenyl)phosphane
現地名: 1,3-ビス(ジフェニルホスフィノ)プロパン
英語名: 1,3-Bis(diphenylphosphino)propane
分子式: C27H26P2
分子量: 412.45

名称と別名

1,3-Bis(diphenylphosphino)propane6737-42-4Phosphine, 1,3-propanediylbis[diphenyl-DPPP cpdPhosphine, 1,3-propanediylbis(diphenyl-44R56E2C68NSC-193753DTXSID0064464RefChem:72524DTXCID30448871,3-B(DPP)PPhosphine, 1,1'-(1,3-propanediyl)bis(1,1-diphenyl)-

名称をさらに表示

1,3-ビス(ジフェニルホスフィノ)プロパンプロパン-1,3-ジイルビス(ジフェニルホスフィン)1,3-ジ(ジフェニルホスフィノ)プロパン(1,3-プロパンジイル)ビス(ジフェニルホスフィン)1,3-プロパンジイルビス(ジフェニルホスフィン)トリメチレンビス(ジフェニルホスフィン)(プロパン-1,3-ジイル)ビス(ジフェニルホスフィン)ビス（ジフェニルホスフィノ）プロパン1,3‐ビス(ジフェニルホスフィノ)プロパン1,3-ビス(ジフェニルホスフィノ)プロパン, 98% DPPPDPPP[3-(ジフェニルホスファニル)プロピル]ジフェニルホスファンジフェニル[3-(ジフェニルホスフィノ)プロピル]ホスフィン1,3-BIS(DIPHENYLPHOSPHINE)PROPANE1,3-Bis(diphenylphosphanyl)propane1,3-bis(diphenyphosphino)propaneBis(1,3-diphenylphosphino)propane98% DPPP1,3-Bis(diphenyLphosphino)propanePH2PCH2 CH2CH2PPH21,3-BIS(DIPHENYPHOSPHINO)

229-791-2DPPP3-diphenylphosphanylpropyl(diphenyl)phosphaneMFCD00003050Trimethylenebis(diphenylphosphine)[3-(diphenylphosphanyl)propyl]diphenylphosphanePropane-1,3-diylbis(diphenylphosphine)1,3-Propanediylbis(diphenylphosphine)

データベース識別子

CAS: 6737-42-4
PubChem CID: 81219
DTXSID: DTXSID0064464
ChEMBL: CHEMBL73394
UNII: 44R56E2C68
EC Number: 229-791-2
Nikkaji: J208.099K

物性

構造計算による物性

XLogP: 6.2
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 8
重原子数: 29
形式電荷: 0
複雑度: 350

物理化学的性質

融点: 63 · 63-65 °C (lit.)
沸点: 529.7 · 529.7±33.0 °C(Predicted)
闪点: 235 °C · 235°C
貯蔵温度: Inert atmosphere,Room Temperature
外見: 顆粒または粉末
色: ホワイト～ライトイエローベージュ
水溶解度: 不溶性
BRN: 2821785 · 2821785
InChI: InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey: LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES: P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS データベース: 6737 · 6737-42-4(CAS DataBase Reference)
NISTの化学物質情報: 1 · 1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPAの化学物質情報: 1 · Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)

化学的性質

化学的特性white to light yellow crystal powde

安全と法規制

GHS分類

GHS Classification · 5 件

Warning

H302 (64.7%): Harmful if swallowed [Warning Acute toxicity, oral]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (64.7%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (99.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H400 (64.7%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]；H410 (65.4%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 153 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory InformationPMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesAcute Tox. 4 (64.7%)；Skin Irrit. 2 (100%)；Skin Sens. 1 (64.7%)；Eye Irrit. 2 (100%)；STOT SE 3 (99.3%)；Aquatic Acute 1 (64.7%)；Aquatic Chronic 1 (65.4%)

法規制情報

Regulatory InformationPMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

安全データ

F: 10-23
wgk: 3
tsca: TSCA listed
hs_code: 29310095
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-37/39-36
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

General Manufacturing InformationPhosphine, 1,1'-(1,3-propanediyl)bis[1,1-diphenyl-: ACTIVE

応用分野 · 3 件

用途触媒及び触媒配位子

説明1,3-Bis(diphenylphosphino)propane is a ligand for metal-catalyzed substitution reactions of aryl and vinyl triflates, halides, and carbonates; carbonylation reactions; Grignard coupling; diene alkylation; macrocycle synthesis.

使用1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

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化合物ノート

読み込み中…

1,3-ビス(ジフェニルホスフィノ)プロパン

基本情報