トリベンジルホスフィン

Phosphine, tris(phenylmethyl)-

HCID 82101

ノート反応

部分構造検索類似構造を探す

基本情報

CAS: 7650-89-7
標準SMILES: c1ccc(CP(Cc2ccccc2)Cc2ccccc2)cc1
InChIKey: IFXORIIYQORRMJ-UHFFFAOYSA-N
分子式: C21H21P
平均分子量: 304.4 g/mol
単同位体質量: 304.1380873

名称と識別子

優先名称: Phosphine, tris(phenylmethyl)-
IUPAC: tribenzylphosphane
現地名: トリベンジルホスフィン
英語名: TRIBENZYLPHOSPHINE
分子式: C21H21P
分子量: 304.37

名称と別名

Tribenzylphosphine7650-89-7Phosphine, tris(phenylmethyl)-EINECS 231-608-6DTXSID9073385RefChem:861962DTXCID3047895231-608-6tribenzylphosphaneTribenzyl phosphineTRYMETHYL PHOSPHINEMFCD00014439

名称をさらに表示

トリベンジルホスフィントリス(フェニルメチル)ホスフィントリスベンジルホスフィンTribenzylphoshineTrisbenzylphosphineTribenzylphosphine 98%TRIBENZYLPHOSPHINE,98%TRIBENZYLPHOSPHINE (TBZP)

Phosphine, tribenzyl-Tris(phenylmethyl)phosphineBn3PTribenzylphosphine, 97%Tribenzylphosphine, 98%(PhCH2)3PSCHEMBL196203HAA65089

データベース識別子

CAS: 7650-89-7
PubChem CID: 82101
DTXSID: DTXSID9073385
EC Number: 231-608-6
Nikkaji: J125.045K

物性

構造計算による物性

XLogP: 4.4
極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 6
重原子数: 22
形式電荷: 0
複雑度: 235

物理化学的性質

融点: 96 · 96-101 °C (lit.)
沸点: 183 · 183-185°C/0.2mm
闪点: 183 · 183-185°C/0.2mm
外見: 結晶性
色: 白い
水溶解度: 水に不溶。
BRN: 650179 · 650179
InChI: 1S/C21H21P/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2
InChIKey: IFXORIIYQORRMJ-UHFFFAOYSA-N
SMILES: C(P(Cc1ccccc1)Cc2ccccc2)c3ccccc3
CAS データベース: 7650 · 7650-89-7(CAS DataBase Reference)
EPAの化学物質情報: Phosphine, tris(phenylmethyl)- (7650-89-7)

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 43 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationPMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

安全データ

F: 10-23
wgk: 3
tsca: TSCA listed
rtecs: SZ3865000
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

General Manufacturing InformationPhosphine, tris(phenylmethyl)-: INACTIVE

応用分野 · 1 件

使用Tribenzylphosphine is used as a co catalyst in preparation of coumarin derivatives via nickel-catalyzed cycloaddition, copolymerization reactions, Rh-catalyzed hydroformylation reactions, preparation of substituted allylamines by three-component coupling of alkynes, imines and organoboranes.