1,1'-(Methylenedi-p-phenylene)bismaleimide (HCID 83648)

名称と識別子

優先名称: 1,1'-(Methylenedi-p-phenylene)bismaleimide
IUPAC: 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione
現地名: 4,4'-ビスマレイミドジフェニルメタン
英語名: Bismaleimide
分子式: C21H14N2O4
分子量: 358.35

名称と別名

1,1'-(Methylenedi-p-phenylene)bismaleimideRefChem:409135Bismaleimide13676-54-54,4'-BismaleimidodiphenylmethaneBismaleimide S1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-4,4'-Methylenebis(N-phenylmaleimide)p,p'-DimaleimidodiphenylmethaneBis(4-maleimidophenyl)methaneDiphenylmethanebismaleimide1,1'-(Methylenedi-4,1-phenylene)bismaleimide

名称をさらに表示

4,4'-ビスマレイミドジフェニルメタン1,1'-[メチレンビス(p-フェニレン)]ビス(1H-ピロール-2,5-ジオン)1,1'-メチレンビス[4-[(2,5-ジヒドロ-2,5-ジオキソ-1H-ピロール)-1-イル]ベンゼン]N,N'-[メチレンビス(1,4-フェニレン)]ジマレインイミド1,1'-[メチレンビス(4,1-フェニレン)]ビス(1H-ピロール-2,5-ジオン)N,N'-(メチレンビス-p-フェニレン)ビス(マレインイミド)N,N'-[メチレンビス(p-フェニレン)]ビス(マレインイミド)1,1'-[メチレンビス(4,1-フェニレン)]ビス(3-ピロリン-2,5-ジオン)N,N'-[メチレンビス(p-フェニレン)]ジマレインイミドビスマレイミドジフェニルメタン1,1'-メチレンビス(4,1-フェニレン)ビス(1H-ピロール-2,5-ジオン)1,1'-[メチレンビス(4,1-フェニレン)]ビス[1H-ピロール-2,5-ジオン]マトリミド5292AN,N'-メチレンビス(4,1-フェニレン)ビス(マレインイミド)1,1'-[メチレンジ(4,1-フェニレン)]ビス(1H-ピロール-2,5-ジオン)1,1'-メチレンビス(1,4-フェニレン)ビス(1H-ピロール-2,5-ジオン)1,1'-[メチレンビス(p-フェニレン)]ジ(1H-ピロール-2,5-ジオン)N,N'-[メチレンビス(4,1-フェニレン)]ビス(マレインイミド)N,N'-[メチレンビス(1,4-フェニレン)]ビス(マレインイミド)1,1'-[メチレンビス(1,4-フェニレン)]ビス(3-ピロリン-2,5-ジオン)BMIbismaleimidesBismaleimide, 4,4'-diphenylmethane1,1’-(methylenedi-1,4-phenylene)bis-1H-pyrrole-2,5-dione1-(4-[4-(2,5-Dioxo-2,5-dihydro-1H-pyrrol-1-yl)benzyl]phenyl)-1H-pyrrole-2,5-dionexu292amb-3000

p,p'-Methylenebis(N-phenylmaleimide)Bis(p-maleimidophenyl)methane1,1'-(Methylenebis(4,1-phenylene))bis(1H-pyrrole-2,5-dione)4,4'-Dimaleimidodiphenylmethane4,4'-Diphenylmethanedimaleimide4,4'-Biphenylmethanebismaleimide4,4'-DiphenylmethanebismaleimideN,N'-Bismaleimido-4,4'-diphenylmethane

データベース識別子

CAS: 13676-54-5
PubChem CID: 83648
DTXSID: DTXSID8044381
ChEMBL: CHEMBL478304
UNII: I67AL345KM
EC Number: 237-163-4
Nikkaji: J208.092C

物性

構造計算による物性

XLogP: 2.1
極性表面積: 74.8 Å²
水素結合供与体数: 0
水素結合受容体数: 4
回転可能結合数: 4
重原子数: 27
形式電荷: 0
複雑度: 614

実験および物理化学的性質

Physical DescriptionDry Powder; Other Solid

Collision Cross Section · 1 件

174.3 Å² [M-H]- [CCS Type: DT; Buffer gas: N2; Ionization: ESI-; Dataset: TOXCAST; Source Identifier: DTXSID8044381]；182.7 Å² [M+Na]+ [CCS Type: DT; Buffer gas: N2; Ionization: ESI+; Dataset: TOXCAST; Source Identifier: DTXSID8044381]；197.5 Å² [M+H]+ [CCS Type: DT; Buffer gas: N2; Ionization: APCI+; Dataset: TOXCAST; Source Identifier: DTXSID8044381]

物理化学的性質

融点: 156 · 156-158 °C(lit.)
沸点: 490.79 °C · 490.79°C (rough estimate)
比重(密度): 1.336 · 1.3360 (rough estimate)
蒸気圧: 0 Pa · 0Pa at 25℃
屈折率: 1.68 · 1.6800 (estimate)
貯蔵温度: Sealed in dry,Room Temperature
溶解性: Water (Slightly)
外見: powder to crystal
酸解離定数(Pka): -0.4 · -0.40±0.20(Predicted)
色: Light yellow to Amber to Dark green
水溶解度: 水に不溶。
BRN: 333986 · 333986
InChI: 1S/C21H14N2O4/c24-18-9-10-19(25)22(18)16-5-1-14(2-6-16)13-15-3-7-17(8-4-15)23-20(26)11-12-21(23)27/h1-12H,13H2
InChIKey: XQUPVDVFXZDTLT-UHFFFAOYSA-N
SMILES: O=C1C=CC(=O)N1c2ccc(Cc3ccc(cc3)N4C(=O)C=CC4=O)cc2
LogP: 1.5 at · 1.5 at 25℃
CAS データベース: 13676 · 13676-54-5(CAS DataBase Reference)
NISTの化学物質情報: p,p'-Bis(N-maleimidophenyl)methane(13676-54-5)
EPAの化学物質情報: 1 H-Pyrrole-2,5-dione, · 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- (13676-54-5)

化学的性質

化学的特性yellow to brownish fine crystalline powder

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H315 (78.7%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (12%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (76.4%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H330 (87.8%): Fatal if inhaled [Danger Acute toxicity, inhalation]；H335 (76.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P260, P261, P264, P264+P265, P271, P272, P280, P284, P302+P352, P304+P340, P305+P351+P338, P316, P319, P320, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 648 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 4 件

Chemical: 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-05-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/11119

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and CategoriesSkin Irrit. 2 (78.7%)；Skin Sens. 1A (12%)；Eye Irrit. 2 (76.4%)；Acute Tox. 2 (87.8%)；STOT SE 3 (76.2%)

法規制情報

Regulatory Information · 4 件

Chemical: 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-05-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/11119

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

安全データ

wgk: 2
tsca: TSCA listed
rtecs: ON5670000
ridadr: UN 2811 6.1/PG 2
hs_code: 29251900
risk_code: 23-36/37/38
化審法: (5)-3377
hazard_code: T
safety_code: 26-45-37/39
hazard_class: 6.1
packing_group: III
Hazard Classifications: Acute Tox. 2 InhalationEye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials

化学と産業

用途と製造

U.S. Production2023: 313,612 lb；2022: 130,706 lb；2021: 163,633 lb；2020: 164,398 lb

Consumer UsesOther

Industry UsesIntermediate；Monomers

General Manufacturing Information · 2 件

Rubber Product Manufacturing；Plastics Material and Resin Manufacturing

1H-Pyrrole-2,5-dione, 1,1'-(methylenedi-4,1-phenylene)bis-: ACTIVE

応用分野

使用Bismaleimide products can be used to make bismaleimide resins, modified phenolic resins, modified epoxy thermosetting resins such as heat resistance and PP, PVC, PBT, PMMA and other plastics, as well as high-grade rubber products.

一般的な説明The thermal and mechanical properties of GEEA cured by 1,1′-(methylenedi-4,1-phenylene)bismaleimide were studied.