Maleimide → Formaldehyde

HRID 1903355

反応式

HRID 1903355 の反応式
C1(=O)N[C:4](=[O:6])C=C1.C1(=O)N([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][N:19]2[C:23](=[O:24])[CH:22]=[CH:21][C:20]2=[O:25])C(=O)C=C1.C1(N2C(=[O:39])C=CC2=O)C=CC=CC=1.C1(N2C(=O)C=CC2=O)C=CC=C(N2C(=O)C=CC2=O)C=1.C1(N2C(=O)C=CC2=O)C=CC(N2C(=O)C=CC2=O)=CC=1.C1C(CC2C=CC(N3C(=O)C=CC3=O)=CC=2)=CC=C(N2C(=O)C=CC2=O)C=1.C(C1C=CC(N2C(=O)C=CC2=O)=C(Cl)C=1)C1C=CC(N2C(=O)C=CC2=O)=C(Cl)C=1>>[NH2:19][C:18]1[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=1.[CH2:4]=[O:6].[C:23]1(=[O:24])[O:25][C:20](=[O:39])[CH:21]=[CH:22]1

参加物

10

反応物 7

HCID 10935Maleimide2 回HCID 13662N-PhenylmaleimideHCID 18156N,N'-1,3-PhenylenedimaleimideHCID 209921,6-BismaleimidohexaneHCID 767651,4-PhenylenebismaleimideHCID 836481,1'-(Methylenedi-p-phenylene)bismaleimideHCID 13809223,3'-Dichloro-4,4'-diphenylmethanedimaleimide

生成物 3

HCID 712FormaldehydeHCID 6115AnilineHCID 7923Maleic Anhydride

実験手順

A maleimide resin composition comprising a maleimide-diamine adduct produced by heating and reacting a reaction mixture comprising at least one maleimide compound selected from the group consisting of N,N'-hexamethylene bismaleimide, N-phenylmaleimide, N,N'-m-phenylene bismaleimide, N,N'-p-phenylene bismaleimide, N,N'-4,4'-diphenylmethane bismaleimide, N,N'-4,4'-diphenyl ether bismaleimide, N,N'-methylene bis(3-chloro-p-phenylene) bismaleimide, N,N'-4,4'-diphenylsulfone bismaleimide, N,N'-4,4'-dicyclo-hexylmethane bismaleimide, N,N'-α,α'-4,4'-dimethylenecyclohexane bismaleimide, N,N'-m-xylene bismaleimide, N,N'-4,4'-diphenylcyclohexane bismaleimide and polyvalent maleimides of the following formula obtained from aniline, formaldehyde condensate and maleic anhydride: ##STR19## with at least one ether bond-containing diamine compound selected from the group consisting of 2,2'-bis[4-(4-aminophenoxy)phenyl]propane, 2,2'-bis[3-methyl-4-(4-aminophenoxy)phenyl]propane, 2,2'-bis[3-chloro-4-(4-aminophenoxy)phenyl]propane, 2,2'-bis[3-bromo-4-(4-aminophenoxy)phenyl]propane, 2,2-bis[3-ethyl-4-(4-aminophenoxy)phenyl]propane, 2,2-bis[3-propyl-4-(4-aminophenoxy)phenyl]propane, 2,2-bis[3-isopropyl-4-(4-aminophenoxy)phenyl]propane, 2,2-bis[3-butyl-4-(4-aminophenoxy)phenyl]propane, 2,2-bis[3-sec.-butyl-4-(4-aminophenoxy)phenyl]propane, 2-2-bis[3-methoxy-4-(4aminophenoxy)phenyl]propane, 1,1-bis[4-(4-aminophenoxy)phenyl]ethane, 1,1-bis[3-methyl-4-(4-aminophenoxy)phenyl]ethane, 1,1-bis[3-chloro-4-(4-aminophenoxy)phenyl]ethane, 1,1-bis[3-bromo-4-(4-aminophenoxy)phenyl]ethane, bis[4-(4-aminophenoxy)phenyl]methane, bis[3-methyl-4-(4-aminophenoxy)phenyl]methane, bis[3-chloro-4-(4-aminophenoxy)phenyl] methane, bis[3-bromo-4-(4-aminophenoxy)phenyl]methane, 1,1,1,3,3-hexafluoro-2, 2-bis[4-(4-aminophenoxy)phenyl]propane, 1,1,1,3,3,3-hexachloro-2, 2-bis[4-(4-aminophenoxy)phenyl]propane, 3,3-bis[4-(4-aminophenoxy)phenyl]pentane, 1,1-bis[4-(4-aminophenoxy)phenyl]propane, 1,1,1,3,3,3-hexafluoro-2,2-bis[3,5-dimethyl-4-(4-aminophenoxy)phenyl]propane, 1,1,1,3,3,3-hexafluoro-2,2-bis-[3,5-dibromo-4-(4-aminophenoxy)phenyl]propane, and 1,1,1,3,3,3-hexafluoro-2,2-bis[3-methyl-4-(4-aminophenoxy)phenyl]propane.

後処理

  1. customproduced
  2. temperatureby heating

出典と根拠

ORDレコード
ord-a78989448ceb41098fefcae0acfc2bb6
出典データセット
uspto-grants-1984_03
特許番号
US04435560

関連ノート

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