Aminopropyltrimethoxysilane (HCID 83756)

概要

reagent for making polymers; structure in first source

名称と識別子

優先名称: Aminopropyltrimethoxysilane
IUPAC: 3-trimethoxysilylpropan-1-amine
現地名: 3-アミノプロピルトリメトキシシラン
英語名: 3-Aminopropyltrimethoxysilane
分子式: C6H17NO3Si
分子量: 179.29

名称と別名

13822-56-53-Aminopropyltrimethoxysilane(3-Aminopropyl)trimethoxysilane3-(Trimethoxysilyl)propylamine3-(Trimethoxysilyl)-1-propanamine1-Propanamine, 3-(trimethoxysilyl)-AminopropyltrimethoxysilaneSilane SC 3900Propylamine, 3-(trimethoxysilyl)-KBE 903SC 39007MRY0C9SB6

名称をさらに表示

3-アミノプロピルトリメトキシシラン(γ-アミノプロピル)トリメトキシシラン(3-アミノプロピル)トリメトキシシラントリメトキシ(3-アミノプロピル)シラン3-(トリメトキシシリル)-1-プロパンアミン3-(トリメトキシシリル)プロピルアミンγ-アミノプロピルトリメトキシシラン[3-(トリメトキシシリル)プロピル]アミン3-(トリメトキシシリル)プロパン-1-アミン3-アミノプロピルメトキシシラン3‐アミノプロピルトリメトキシシランアミノプロピルトリメトキシシランAPTMS3-(trimethoxysilyl)-1-propanaminγ-AminopropyltrimethoxysilaneA-1110CA0880KH0540

TMSPA cpdGENIOSIL GF 96NSC-838453-(aminopropyl)trimethoxysilaneRefChem:915703APS-3237-511-53-(Trimethoxysilyl)propan-1-amine

データベース識別子

CAS: 13822-56-5
PubChem CID: 83756
DTXSID: DTXSID0038833
UNII: 7MRY0C9SB6
EC Number: 237-511-5
Nikkaji: J209.066J

物性

構造計算による物性

極性表面積: 53.7 Å²
水素結合供与体数: 1
水素結合受容体数: 4
回転可能結合数: 6
重原子数: 11
形式電荷: 0
複雑度: 89.6

実験および物理化学的性質

Chemical ClassesMetals -> Metalloid Compounds (Silicon)

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

Physical Description · 2 件

Liquid

Clear to straw-colored liquid with an ammoniacal odor; [Gelest MSDS]

物理化学的性質

融点: -60 °C · <-60°C
沸点: 91 · 91-92 °C15 mm Hg(lit.)
比重(密度): 1.027 g/mL · 1.027 g/mL at 25 °C(lit.)
蒸気圧: 0 · 0-12790Pa at 20-25℃
屈折率: 20 · n20/D 1.424(lit.)
闪点: 182 °F · 182 °F
貯蔵温度: 30 °C · Store below +30°C.
溶解性: クロロホルム（微量）、メタノール（微量）
外見: 液体
酸解離定数(Pka): 10.61 · 10.61±0.10(Predicted)
色: 無色透明
比重: 1.027 · 1.027
PH: 9 · >9 (20g/l, H2O, 20℃)
臭い (Odor): Ammoniacal odor
水溶解度: 反応する
BRN: 2038118 · 2038118
安定性: 安定していますが、水分に敏感です。水、強酸、強酸化剤とは混和しません。可燃性。
化粧品成分の機能: スキンコンディショニング - その他
InChI: 1S/C6H17NO3Si/c1-8-11(9-2,10-3)6-4-5-7/h4-7H2,1-3H3
InChIKey: SJECZPVISLOESU-UHFFFAOYSA-N
SMILES: CO[Si](CCCN)(OC)OC
LogP: -4 · -4--0.82 at 20℃
CAS データベース: 13822 · 13822-56-5(CAS DataBase Reference)
NISTの化学物質情報: 1 · 1-Propanamine, 3-(trimethoxysilyl)-(13822-56-5)
EPAの化学物質情報: 1 · 1-Propanamine, 3-(trimethoxysilyl)- (13822-56-5)

化学的性質

化学的特性Colorless transparent liquid

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 2.1% (22 of 1053) of reports.

Danger

H314 (48.7%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P321, P332+P317, P337+P317, P362+P364, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1053 reports by companies from 19 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 4 件

Chemical: 1-Propanamine, 3-(trimethoxysilyl)-

1-Propanamine, 3-(trimethoxysilyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Propanamine, 3-(trimethoxysilyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 05-01-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14372

3-(Trimethoxysilyl)-propylamine: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to environment

Hazards Summary · 1 件

Reacts with water and moisture producing methanol; Vapor causes severe eye irritation; Liquid causes severe conjunctivitis and corneal damage; May cause skin irritation and contact dermatitis; A respiratory tract irritant; Oral toxicity associated with the hydrolysis product methanol; [Gelest MSDS] See Methyl alcohol. See 3-Chloropropyltrimethoxysilane.

Hazard Classes and CategoriesSkin Corr. 1 (48.7%)

安全と保護具

Protective Action Criteria (PAC) · 3 件

9.0 [mg/m3]

99 [mg/m3]

600 [mg/m3]

安全データ

F: 1-10
wgk: 3
tsca: TSCA listed
ridadr: UN2735
hs_code: 29310095
risk_code: 36/38-34-41-38
化審法: (2)-2061
消防法: 危-4-3-III
hazard_code: Xi,C
safety_code: 26-45-36/37/39-25-39
hazard_class: 8
自然発火温度: 295 °C
Hazard Classifications: Eye Dam. 1Skin Irrit. 2
ストレージクラス: 10 - Combustible liquids

化学と産業

用途と製造

UsesPermitted for use as an inert ingredient in non-food pesticide products; [EPA]

U.S. Production2023: 1,000,000 - <5,000,000 lb

Consumer UsesBinder

Industry UsesAdhesion/cohesion promoter

Household ProductsInformation on 6 consumer products that contain 3-Aminopropyltrimethoxysilane in the following categories is provided:

General Manufacturing Information · 2 件

Rubber Product Manufacturing

1-Propanamine, 3-(trimethoxysilyl)-: ACTIVE

応用分野 · 3 件

用途有機合成原料。

使用(3-Aminopropyl)trimethoxysilane is used as a silane coupling agent on silver nanoparticles. It is also used in silanization processes. It is also used to prepare surface modified titanate nanotubes (TiNT).

一般的な説明(3-Aminopropyl)trimethoxysilane(APTMS) is an amino-silane that is mainly used as a silane coupling agent for the surface modification of a variety of nanomaterials. APTMS based films form a thermally stable layer on different substrates.