テレフタル酸ジメチル

Fire Extinguishing Agents: Water, dry chemical, foam, carbon dioxide (USCG, 1999)

Use water spray, foam, powder, carbon dioxide.

Fresh air, rest.

Rinse and then wash skin with water and soap.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth.

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Extinguish with water, dry chemicals, foam, or carbon dioxide.

From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors, or shows any signs of deforming), withdraw immediately to a secure position.

Alcohol foam. Water or foam may cause frothing.

Dimethyl terephthalate is stored molten in insulated heated tanks, and is perferentially shipped molten in insulated rail tank cars or tank trucks. It is also solidified into briquettes or flakes, and shipped in 1 ton or 25 kg bags.

Store in tightly closed containers in a cool, well-ventilated area away from oxidizers, nitrates, acids and sources of ignition

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then dampen the solid spill material with toluene, then transfer the dampened material to a suitable container. Use absorbent paper dampened with toluene to pick up any remaining material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent-wash all contaminated surfaces with toluene followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

LC50 Pimephales promelas (fathead minnow) 9.6 mg/L/96 hr, static

LC50 Daphnia magna (water flea) 30.4 mg/L/48 hr /Conditions of bioassay not specified in source examined/

LC50 Daphnia magna (water flea) > 100 mg/L/96 hr, static

LC50 Dugesia tigrina (flatworm) > 100 mg/L/96 hr, static

For more Ecotoxicity Values (Complete) data for DIMETHYL TEREPHTHALATE (8 total), please visit the HSDB record page.

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 400(SRC), determined from a log Kow of 2.25(2) and a regression-derived equation(3), indicates that dimethyl terephthalate is expected to have moderate mobility in soil(SRC). Volatilization of dimethyl terephthalate from moist soil surfaces is expected to be an important fate process(SRC) given a Henry's Law constant of 1.3X10-4 atm-cu m/mole(SRC), derived from its vapor pressure, 0.01 mm Hg(4), and water solubility, 19 mg/L(5). Dimethyl terephthalate is not expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure(4). Dimethyl terephthalate, at a concentration of 0.5%, degraded completely in 15 days at 30 °C in soil with a pH of 8.2 and 60% moisture content(6).

AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 400(SRC), determined from a log Kow of 2.25(2) and a regression-derived equation(3), indicates that dimethyl terephthalate is expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(3) based upon a Henry's Law constant of 1.3X10-4 atm-cu m/mole(SRC), derived from its vapor pressure, 0.01 mm Hg(4), and water solubility, 19 mg/L(5). Using this Henry's Law constant and an estimation method(3), volatilization half-lives for a model river and model lake are 13 hours and 8.3 days, respectively(SRC). According to a classification scheme(6), an estimated BCF of 11(SRC), from its log Kow(2) and a regression-derived equation(7), suggests the potential for bioconcentration in aquatic organisms is low(SRC). A 3 day river die-away test using 50, 40, and 5 ppm dimethyl terephthalate resulted in 100% biodegradation in all three tests of river water, and 27, 38, and 49% biodegradation in the three tests of sea water(8) suggesting dimethyl terephthalate is expected to biodegrade in aquatic environments(SRC).

ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), dimethyl terephthalate, which has a vapor pressure of 0.01 mm Hg at 25 °C(2), is expected to exist solely as a vapor in the ambient atmosphere. Vapor-phase dimethyl terephthalate is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 28 days(SRC), calculated from its rate constant of 5.7X10-13 cu cm/molecule-sec at 25 °C(SRC) that was derived using a structure estimation method(3). Dimethyl terephthalate does contain chromophores that absorb at wavelengths >290 nm(4) and therefore may be susceptible to direct photolysis by sunlight(SRC).

/PLANTS/ Ryegrass, radish, lettuce /were tested in/ 7-Day germination exposures to /dimethyl terephthalate/ concentrations of 0, 1, 10, 100, or 1000 mg/L. There were 80 seeds used for each exposure test level and 40 seeds for control. ... No Adverse Effect Concn: 10 mg/L (rye grass, radish ), 1 mg/L (lettuce).

/PLANTS/ Corn, marigold, lettuce, radish /seedlings were tested in/ 1-week phytotoxicity /aasays/ to /dimethyl terephthalate/ concentrations of 0, 100, and 1000 mg/L. There were 10 corn seedlings and 20 seedlings for the other species per exposure level. ... No Adverse Effect Concn: >1000 mg/L (radish, marigold, lettuce), >100 mg/L (corn).

The following link will take the user to the National Toxicology Program (NTP) Test Agent Search Results page, which tabulates all of the "Standard Toxicology & Carcinogenesis Studies", "Developmental Studies", and "Genetic Toxicity Studies" performed with this chemical. Clicking on the "Testing Status" link will take the user to the status (i.e., in review, in progress, in preparation, on test, completed, etc.) and results of all the studies that the NTP has done on this chemical. [http://ntp-apps.niehs.nih.gov/ntp_tox/index.cfm?fuseaction=ntpsearch.searchresults&searchterm=120-61-6]

The concentration of dimethyl terephthalate in the waste water from a dimethyl terephthalate manufacturing plant was less than 0.5 mg/L whereas its acid was found at 459 mg/L(1). This is due to the hydrolysis of dimethyl terephthalate to the acid(1). Dimethyl terephthalate was identified in an industrial wastewater survey sample extracts at a concentration of 557 ng/uL in the organics industry and 21 ng/uL in the organics and plastics industry(2). Dimethyl terephthalate was identified, not quantified, in advanced waste treatment concentrates in Lake Tahoe, CA and in Pomona, CA(3).

Dimethyl terephthalate (DMT)

Urinary

1 x 10 ^-1 mg/kg-day

The Koc of dimethyl terephthalate is estimated as 400(SRC), using a log Kow of 2.25(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that dimethyl terephthalate is expected to have moderate mobility in soil.

/HUMAN EXPOSURE STUDIES/ An oily paste containing 80% DMT showed no irritant effects 24 hr after 10 applications to human skin.

/OTHER TOXICITY INFORMATION/ ... Calculations based on the solubility of calcium terephthalate indicate that humans would have to absorb at least 2.0 grams per day terephthalic acid or 2.5 grams per day dimethyl terephthalate to develop bladder stones.

This action promulgates standards of performance for equipment leaks of Volatile Organic Compounds (VOC) in the Synthetic Organic Chemical Manufacturing Industry (SOCMI). The intended effect of these standards is to require all newly constructed, modified, and reconstructed SOCMI process units to use the best demonstrated system of continuous emission reduction for equipment leaks of VOC, considering costs, non air quality health and environmental impact and energy requirements. Dimethyl terephthalate is produced, as an intermediate or a final product, by process units covered under this subpart.

Used to make polyester resins (polyethylene terephthalate for film and fibers); [Hawley]

Polyester resins for film and fiber production, especially polyethylene terephthalate; intermediate.

For use in polymer fibers, polyethylene terphthalate (PET) solid-state resins, polyester film, polybutylene terephthalate and PET engineering resins, and miscellaneous including cyclohexanedimethanol, terephthaloyl chloride, copolyester-ether elastomers, plasticizers, and liquid crystal polymers.

Dimethyl terephthalate is used as an industrial intermediate to manufacture polyethylene terephthalate (PET) and dioctyl terephthalate. ...

... Used to make saturated polyesters with aliphatic diols as the comonomer.

PRODUCT PROFILE: DMT /dimethyl terephthalate/. Dimethyl terephthalate (DMT) is used mainly to produce polyester resins, fibres, and films as well as engineering resins. The polyesters produced are used in fibres for the textile industry, the manufacture of food and drink containers such as polyethylene terephthalate (PET) bottles, and films used in photography, computers, audio-visual equipment and packaging.

(1972) 5.25X10+10 GRAMS

(1975) 9.4X10+10 GRAMS

CHEMICAL PROFILE: PTA /purified terephthalic acid/ - DMT /dimethyl terephthalate/: US Exports: 1994: 1,095 million pounds

CHEMICAL PROFILE: PTA /purified terephthalic acid/ - DMT /dimethyl terephthalate/: Dimethyl terephthalate: US Exports: 1999: 13 million pounds; 2000: 10 million pounds

For more U.S. Exports (Complete) data for DIMETHYL TEREPHTHALATE (6 total), please visit the HSDB record page.

(1975) 9.4X10+10 GRAMS

CHEMICAL PROFILE: PTA /purified terephthalic acid/ - DMT /dimethyl terephthalate/: Dimethyl terephthalate: US Imports: 1999: 6 million pounds; 2000: 9 million pounds

CHEMICAL PROFILE: PTA /purified terephthalic acid/ - DMT /dimethyl terephthalate/: Dimethyl terephthalate: US Imports: 2002: 2 million pounds; 2003: 1 million pounds

CHEMICAL PROFILE: PTA /purified terephthalic acid/ and DMT /dimethyl terephthalate/. Dimethyl terephthalate: US Imports: 2005: 2.3 million pounds; 2006: 4.3 million pounds

2023: 1,000,000,000 - <2,500,000,000 lb

(1972) 1.03X10+12 GRAMS

3.270734X10+9 kg including acid (1976)

2454X10+3 tons including acid (1977)

1,449,828X10+3 kg (1993)

For more U.S. Production (Complete) data for DIMETHYL TEREPHTHALATE (14 total), please visit the HSDB record page.

(DIMETHYL TEREPHTHALATE & TEREPHTHALIC ACID) ABOUT 93% AS A MONOMER IN POLYESTER FIBER PRODUCTION; ABOUT 7% AS A MONOMER IN POLYESTER FILM PRODUCTION; LESS THAN 1% AS A MONOMER IN PRODUCTION OF POLYBUTYLENE TEREPHTHALATE & OTHER, SMALL VOLUME RESINS (1973)

CHEMICAL PROFILE: PTA /purified terephthalic acid/ - DMT /dimethyl terephthalate/. End-use pattern for PTA+DMT in 1995

CHEMICAL PROFILE: PTA /purified terephthalic acid/ - DMT /dimethyl terephthalate/: US Demand: 1994: 8,500 million pounds; 1995: 8,755 million pounds; 1999: 9,850 million pounds /projected/

CHEMICAL PROFILE: PTA /purified terephthalic acid/ - DMT /dimethyl terephthalate/. End-use pattern for PTA+DMT in 1998

For more Consumption Patterns (Complete) data for DIMETHYL TEREPHTHALATE (13 total), please visit the HSDB record page.

... Produced by oxidation of the methyl groups on ... p-xylene ... . After oxidation to a carboxylic acid, reaction with methanol gives the methyl ester, dimethyl terephthalate.

Oxidation of para-xylene or mixed xylene isomers, followed by esterification.

PRODUCT PROFILE: DMT /dimethyl terephthalate/. The traditional process to manufacture /dimethyl terephthalate/ is by esterification of /purified terephthalic acid/ with methanol generated by the catalytic homogeneous oxidation of /paraxylene/. The most widely used technology is based on /paraxylene/ using oxidation and esterification steps. /Paraxylene/ is oxidised in the liquid phase by air in the presence of a cobalt salt catalyst to form an oxidate containing p-toluic acid and monomethyl terephthalate. Esterification is carried out in the presence of methanol to form /dimethyl terephthalate/.

Synthetic Dye and Pigment Manufacturing

1,4-Benzenedicarboxylic acid, 1,4-dimethyl ester: ACTIVE

/POLYESTER/ FIBERS...ARE FORMED OF POLYETHYLENE TEREPHTHALATE. THIS POLYMER IS PRODUCED FROM DIMETHYL TEREPHTHALATE & ETHYLENE GLYCOL...

1978 capacity = 3.2X10+6 tons/year (includes acid)