Methyl phenylglyoxalate (HCID 84835)

名称と識別子

優先名称: Methyl phenylglyoxalate
IUPAC: methyl 2-oxo-2-phenylacetate
英語名: methyl 2-oxo-2-phenyl-acetate
分子式: C9H8O3
分子量: 0

名称と別名

Methyl benzoylformate15206-55-0methyl 2-oxo-2-phenylacetateMethyl phenylglyoxalateMethyl oxophenylacetateMethyl phenylglyoxylateBenzoylformic acid methyl esterPhenylglyoxylic acid methyl esterPhenylglyoxylic acid, methyl esterBenzeneacetic acid, .alpha.-oxo-, methyl estermethyl oxo(phenyl)acetateGlyoxylic acid, phenyl-, methyl ester

名称をさらに表示

NSC 171206alpha-oxobenzeneacetic acid methyl ester23F2045STGBenzeneacetic acid, alpha-oxo-, methyl esterEINECS 239-263-3NSC-171206NSC-4098812-Oxo-2-phenylacetic acid methyl ester

データベース識別子

CAS: 15206-55-0、81065-82-9
PubChem CID: 84835
DTXSID: DTXSID9065867
ChEBI: CHEBI:84256
UNII: 23F2045STG
EC Number: 239-263-3
Nikkaji: J60.885H

物性

構造計算による物性

XLogP: 1.7
極性表面積: 43.4 Å²
水素結合供与体数: 0
水素結合受容体数: 3
回転可能結合数: 3
重原子数: 12
形式電荷: 0
複雑度: 180

実験および物理化学的性質

Physical DescriptionLarge Crystals; Liquid

Kovats Retention Index1335.1

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 17.1% (48 of 280) of reports.

Warning

H315 (26.4%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (56.1%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (26.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (26.4%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 280 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Reported as not meeting GHS hazard criteria per 48 of 280 reports by companies.；There are 6 notifications provided by 232 of 280 reports by companies with hazard statement code(s).；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 4 件

Chemical: Benzeneacetic acid, .alpha.-oxo-, methyl ester

Benzeneacetic acid, .alpha.-oxo-, methyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzeneacetic acid, .alpha.-oxo-, methyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 19-09-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/16435；Status: Cease Manufacture Update: 18-04-2013 https://echa.europa.eu/registration-dossier/-/registered-dossier/6562

Benzeneacetic acid, .alpha.-oxo-, methyl ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and CategoriesSkin Irrit. 2 (26.4%)；Skin Sens. 1 (56.1%)；Eye Irrit. 2A (26.8%)；STOT SE 3 (26.4%)

法規制情報

Regulatory Information · 4 件

Chemical: Benzeneacetic acid, .alpha.-oxo-, methyl ester

Benzeneacetic acid, .alpha.-oxo-, methyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzeneacetic acid, .alpha.-oxo-, methyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 19-09-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/16435；Status: Cease Manufacture Update: 18-04-2013 https://echa.europa.eu/registration-dossier/-/registered-dossier/6562

Benzeneacetic acid, .alpha.-oxo-, methyl ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

化学と産業

用途と製造

U.S. Production2023: 100,000 - <250,000 lb；2022: 50,000 - <75,000 lb；2021: 100,000 - <250,000 lb；2020: 25,000 - <50,000 lb

Consumer UsesPhotosensitive agent；Not Known or Reasonably Ascertainable

Industry UsesTanning agents not otherwise specified；Photosensitive agent；Not Known or Reasonably Ascertainable

General Manufacturing Information · 2 件

Adhesive Manufacturing；Not Known or Reasonably Ascertainable；Plastics Material and Resin Manufacturing；Paint and Coating Manufacturing；Printing Ink Manufacturing

Benzeneacetic acid, .alpha.-oxo-, methyl ester: ACTIVE