Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester (HCID 85963)

概要

This liquid peroxide is particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently. They are generally stored or transported in a solvent slurry.

名称と識別子

優先名称: Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester
IUPAC: 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate
現地名: ペルオキシビス(ぎ酸2-エチルヘキシル)
英語名: Di-(2-ethylhexyl)peroxydicarbonate
分子式: C18H34O6
分子量: 346.46

名称と別名

16111-62-9Peroxydicarbonic acid, bis(2-ethylhexyl) esterDi(2-ethylhexyl) peroxydicarbonateBis(2-ethylhexyl) peroxydicarbonateEINECS 240-282-4BRN 5964960di-(2-Ethylhexyl)peroxydicarbonateDTXSID5027778Peroxydicarbonic acid, di(2-ethylhexyl) esterEC 240-282-4Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) esterDI-(2-ETHYLHEXYL) PEROXYDICARBONATE, (TECHNICALLY PURE)

名称をさらに表示

ペルオキシ二炭酸ビス(2-エチルヘキシル)ペルオキシビス(ぎ酸2-エチルヘキシル)ペルオキシジ炭酸ビス(2-エチルヘキシル)ペルオキシ二炭酸ジ(2-エチルヘキシル)ペルオキシビス[ぎ酸(2-エチルヘキシル)]過二炭酸ジ-2-エチルヘキシル1,1'-[ペルオキシビス(カルボニルオキシ)]ビス(2-エチルヘキサン)ビス（2エチルヘキシル）パ-オキシジカ-ボネ-トビス(2-エチルヘキシル)パーオキシジカーボネートビス（２エチルヘキシル）＝ペルオキシジカルボナトC，C’-ビス（2-エタン-1-イルヘキサ-1-イル）＝ペルオキシジカルボナート1,1′-[ペルオキシビス(カルボニルオキシ)]ビス(2-エチルヘキサン)2-エチルヘキシルパージカーボネート3-({[({[(2-エチルヘキシル)オキシ]カルボニル}ペルオキシ)カルボニル]オキシ}メチル)ヘプタンLupersol 223Trigonox EHP-C75Trigonox EHP-W60Trigonox EHPS-C75Initiating agent EHPDEHP peroxydicarbonate2-Ethylhexyl percarbonateBis(2-ethylhexyl) perdicarbonate

DI-(2-ETHYLHEXYL) PEROXYDICARBONATE, [TECHNICALLY PURE]RefChem:860365ESPERCARB 840MTRIGONOX EHP-W 40DTXCID407778di-2-ethylhexyl peroxydicarbonate240-282-42-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate

データベース識別子

CAS: 16111-62-9
PubChem CID: 85963
DTXSID: DTXSID5027778
EC Number: 240-282-4
Nikkaji: J9.287H

物性

構造計算による物性

XLogP: 7.3
極性表面積: 71.1 Å²
水素結合供与体数: 0
水素結合受容体数: 6
回転可能結合数: 17
重原子数: 24
形式電荷: 0
複雑度: 299

実験および物理化学的性質

Physical Description · 2 件

This liquid peroxide is particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently. They are generally stored or transported in a solvent slurry.

Liquid; CBI

物理化学的性質

沸点: 401.18 °C · 401.18°C (rough estimate)
比重(密度): 1.0722 · 1.0722 (rough estimate)
蒸気圧: 0.001 Pa · 0.001Pa at 25℃
屈折率: 1.445 · 1.4450 (estimate)
水溶解度: 880 mg/L · 880mg/L at 25℃
安定性: 加熱すると不安定。加熱すると爆発の危険性があります。衝撃に弱い場合があります。可燃性。有機物と激しく反応することがある。
LogP: 2.73 · 2.73
EPAの化学物質情報: Peroxydicarbonic acid, bis(2-ethylhexyl) ester (16111-62-9)

化学的性質 · 1 件

化学的特性It is colorless liquid with unpleasant odor. Thermally unstable with required continuous refrigeration below -10°C (-14°F). Refer to the Code for the Storage of Organic Peroxide Formulations. Storage incompatibility includes strong acids, oxidizing agents, alkaline materials, reducing agents, and amines. Also, it should be stored away from excessive heat, sources of ignition, and reactive materials (12b).

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H242 (100%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]

P210, P234, P235, P240, P261, P264, P264+P265, P270, P272, P280, P301+P317, P302+P352, P305+P351+P338, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P370+P378, P403, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 559 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 4 件

Chemical: Peroxydicarbonic acid, bis(2-ethylhexyl) ester

Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 31-05-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/14207

Peroxydicarbonic acid, bis(2-ethylhexyl) ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

DOT LabelOrganic Peroxide

Fire HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Health HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Reactive GroupPeroxides, Organic

Reactivity AlertsExplosive

安全と保護具

Fire FightingExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

First AidExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Nonfire Spill ResponseExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Isolation and EvacuationExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

Personal Protective Equipment (PPE)Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

安全データ

tsca: TSCA listed
ridadr: 3117
hazard_class: 5.2
packing_group: II

化学と産業

用途と製造

U.S. Production2023: 4,000,000 - <5,500,000 lb

Consumer UsesNot Known or Reasonably Ascertainable

Industry UsesPolymerization promoter

General Manufacturing Information · 2 件

Plastics Material and Resin Manufacturing

Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester: ACTIVE

応用分野

一般的な説明Di-(2-ethylhexyl)peroxydicarbonate is particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently. They are generally stored or transported in a solvent slurry.