Vinyl Chloride → Vinyl chloride-vinyl acetate

An autoclave equipped with a stirrer was charged with methanol, vinyl chloride, vinyl acetate, di(2-ethylhexyl) peroxydicarbonate and partially saponified polyvinyl alcohol, and the temperature was elevated to 60° C. with stirring under an atmosphere of nitrogen gas to initiate the reaction, followed by further continuous injection of vinyl chloride to conduct the copolymerization reaction. After release of the residual pressure of the autoclave and cooling, a copolymer slurry was taken out and filtered, followed by washing with methanol three times and further with deionized water twice. Then, the resulting product was filtered and dried to obtain a vinyl chloride-vinyl acetate copolymer powder. This copolymer, methanol, N,N-dimethylethanolamine and sodium hydroxide were added to a reactor equipped with a cooling pipe, and were allowed to react at 40° C. Then, the reaction product was cooled, and acetic acid was added thereto to neutralize unreacted sodium hydroxide. The resulting product was washed with methanol three times and further with deionized water twice, followed by filtering and drying to obtain a vinyl chloride-vinyl acetate-vinyl alcohol-N,N-dimethylethanolamine-modified vinyl unit copolymer powder.

1. customAn autoclave equipped with a stirrer
2. customwas elevated to 60° C.
3. customthe reaction
4. customthe copolymerization reaction
5. temperatureAfter release of the residual pressure of the autoclave and cooling
6. filtrationfiltered
7. washby washing with methanol three times and further with deionized water twice
8. filtrationThen, the resulting product was filtered
9. customdried

ORDレコード

ord-c36662992a3545c8b6b291a9d630e928

出典データセット

uspto-grants-2000_05

DOI

10.6084/m9.figshare.5104873.v1

特許番号

US06063500