データを補完しています。通常は 1 分以内に完了します
基本情報
- 標準SMILES
CC(COc1ccc(C(C)(C)C)cc1)OS(=O)OCCCl- InChIKey
YKFRAOGHWKADFJ-UHFFFAOYSA-N- 分子式
- C15H23ClO4S
- 平均分子量
- 334.865 g/mol
- 単同位体質量
- 334.1005579
名称と識別子
- 優先名称
- Aramite
- IUPAC
- 1-(4-tert-Butylphenoxy)propan-2-yl 2-chloroethyl sulfite
- 現地名
- 亜硫酸O-(2-クロロエチル)O-[2-[4-(1,1-ジメチルエチル)フェノキシ]-1-メチルエチル]
- 英語名
- ARAMITE
- 分子式
- C15H23ClO4S
- 分子量
- 334.86
名称と別名
名称をさらに表示
データベース識別子
- CAS
140-57-8- PubChem CID
- 8809
- DTXSID
DTXSID3020097- ChEMBL
CHEMBL1903447- ChEBI
CHEBI:82151- UNII
- 55619R6X8S
- EC Number
- 690-073-0
- Nikkaji
- J5.807F
物性
物理化学的性質
- 融点
- -31.7 ° · -31.7°
- 沸点
- 0.1 · bp0.1 175°; bp7.0 200-210°
- 比重(密度)
- 1.195 · 1.195
- 屈折率
- 20 · nD20 1.5100 to 1.5118; nD27 1.5075
- 貯蔵温度
- 2 · 2-8°C
- 溶解性
- クロロホルム(微量)、メタノール(微量)
- 外見
- 油
- 色
- 無色~淡褐色
- Henry's Law Constant
- 5.2 · 5.2×101 mol/(m3Pa) at 25℃, HSDB (2015)
- 安定性
- Hygroscopic
- 主な用途
- 環境
- InChI
- 1S/C15H23ClO4S/c1-12(20-21(17)19-10-9-16)11-18-14-7-5-13(6-8-14)15(2,3)4/h5-8,12H,9-11H2,1-4H3
- InChIKey
- YKFRAOGHWKADFJ-UHFFFAOYSA-N
- EPAの化学物質情報
- Aramite (140-57-8)
化学的性質
化学的特性Aramite is a heavy, dark-amber liquid.
安全と法規制
安全データ
- wgk
- 2
- ridadr
- UN 1208 3/PG 2
- 毒性
- LD50 orally in rats: 3.90±0.28 g/kg (Oser, Oser)
- hs_code
- 29252900
- risk_code
- 11-36/37/38-48/20-62-40
- hazard_code
- F,Xn
- safety_code
- 53-16-36/37/39-45-36/37-24/25-23
- Hazard Classifications
- Carc. 2Eye Irrit. 2Skin Irrit. 2STOT SE 3
- ストレージクラス
- 6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
- 有毒物質データの
- 140-57-8(Hazardous Substances Data)
化学と産業
応用分野
説明Aramite is a synthetic chlorinated hydrocarbon with molecular weight of 334.87 and density of 1.143 at 20°C. It is a clear, light-colored oil with melting point of 37.3 C and boiling point of 175 °C at 0.1 mm Hg. The technical grade aramite is a dark amber liquid. Aramite is soluble at 0.000 1% (practically insoluble) in water but is miscible in many organic solvents. It was sold as mixture in organic solvents at different strengths for further dilution and use. Aramite was used as a pesticide (acaricide) to control mites in plants and animals. Aramite was initially introduced to market around 1950. It was mostly used between 1950 and 1954 in greenhouses in the United States. Its manufacture and use were voluntarily discontinued due to its carcinogenic potential according to a US Environmental Protection Agency (EPA) notice dated 12 April 1977. However, there are reports of bans of aramite use in a few European countries, in 1987 (Lithuania), 1996 (Poland), and 1999 (Estonia). There is no information on the production, import, registration, marketing, stockpiling, and use of aramite in Russia. Occupational exposure through dermal contact and inhalation was possible during its use.
使用Aramite was formerly used in control of mites (miticide) in citrus fruits, vegetables, and animals. Active mite stage was most sensitive to aramite toxicity. The death in mites was due to paralysis and disorganized movements of appendages, leading to detachment from the plant. Insects and mites other than Tetracychidae are not as sensitive to aramite. Mites exposed in the field to up to 21 applications were not found to develop resistance in mites, unlike other organochlorines where insects develop resistance rapidly. Aramite is rendered inactive when mixed with lime and other alkaline materials. Aramite was used in combination of other pesticides to control a wide range of mite species.
一般的な説明Aramite is a carcinogenic acaricide, widely used against six spotted mite, European red mite and others affecting crops.
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