Ethylenediamine Dihydrochloride (HCID 9521)

名称と識別子

優先名称: Ethylenediamine Dihydrochloride
IUPAC: ethane-1,2-diamine;dihydrochloride
現地名: エチレンジアミン二塩酸塩
英語名: Ethylenediamine dihydrochloride
分子式: C2H10Cl2N2
分子量: 133.02

名称と別名

Ethylenediamine dihydrochloride333-18-6Ethylenediammonium dichloride1,2-Diaminoethane dihydrochlorideEthylenediammonium chlorideDimethylenediamine dihydrochlorideEthylenediamine, dihydrochlorideCHEBI:5362691WQV43244DTXSID5043920NSC-163962RefChem:139151

名称をさらに表示

エチレンジアミン二塩酸塩エチレンジアミン·二塩酸塩エチレンジアミン·2塩酸塩エチレンジアミン·2塩酸1,2-エタンジアミン·二塩酸塩ETHYLENE DIAMINE DIHYDROCHLORIDE (100 ΜG/ML IN MEOH)エチレンジアンモニウムジクロリドエチレンジアミン二塩酸塩ETHYLENEDIAMINE 2HCLEthylenediaminehydrochlorideEthylenediamine dihyenediamine dihydrochLETHYLENEDIAMINE DI HCLEthylenediamine dichloride

DTXCID3023920206-369-6ethane-1,2-diamine dihydrochlorideChlor-ethamine1,2-Ethanediamine, dihydrochlorideethane-1,2-diamine;dihydrochlorideMFCD00012524Dimethylenediamine diydrochloride

データベース識別子

CAS: 333-18-6
PubChem CID: 9521
DTXSID: DTXSID5043920
ChEBI: CHEBI:53626
UNII: 91WQV43244
EC Number: 206-369-6

物性

構造計算による物性

極性表面積: 52 Å²
水素結合供与体数: 4
水素結合受容体数: 2
回転可能結合数: 1
重原子数: 6
形式電荷: 0
複雑度: 6

実験および物理化学的性質

Physical DescriptionWhite crystalline solid; Hygroscopic; [Sigma-Aldrich MSDS]

物理化学的性質

融点: 300 °C · >300 °C(lit.)
比重(密度): 1.46 g/cm3 · 1.46 g/cm3
貯蔵温度: 30 °C · Store below +30°C.
溶解性: 100 mg/mL · 水：可溶100mg/mL 無色透明～微微黄色
外見: 結晶性粉末
色: ホワイトからオフホワイト
PH: 5 · 5 (100g/l, H2O, 20℃)
水溶解度: 300 g/L · 300g/L(20℃)
BRN: 3665235 · 3665235
安定性: 安定。強力な酸化剤とは相容れない。
InChI: InChI=1S/C2H8N2.2ClH/c3-1-2-4;;/h1-4H2;2*1H
InChIKey: OHHBFEVZJLBKEH-UHFFFAOYSA-N
SMILES: C(N)CN.Cl.Cl
CAS データベース: 333 · 333-18-6(CAS DataBase Reference)
EPAの化学物質情報: Ethylenediamine dihydrochloride (333-18-6)

化学的性質

化学的特性white crystalline powder

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H302 (94.4%): Harmful if swallowed [Warning Acute toxicity, oral]；H315 (93%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (93%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (93%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H334 (88.7%): May cause allergy or asthma symptoms or breathing difficulties if inhaled [Danger Sensitization, respiratory]；H335 (88.7%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P233, P260, P261, P264, P264+P265, P270, P271, P272, P280, P284, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 71 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 2 件

Chemical: 1,2-Ethanediamine, dihydrochloride

Ethylenediammonium dichloride: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 件

Causes allergic dermatitis in 48-hr constant dermal studies of humans; [RTECS] A skin and strong eye irritant; May cause skin and respiratory sensitization; Harmful by ingestion; Reproductive and developmental toxicity observed in experimental animals; [Sigma-Aldrich MSDS] See Ethylenediamine.

Hazard Classes and CategoriesAcute Tox. 4 (94.4%)；Skin Irrit. 2 (93%)；Skin Sens. 1 (93%)；Eye Irrit. 2A (93%)；Resp. Sens. 1 (88.7%)；STOT SE 3 (88.7%)

安全と保護具

Protective Action Criteria (PAC) · 3 件

2.7 [mg/m3]

29 [mg/m3]

180 [mg/m3]

毒性情報

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.；Asthma - Reversible bronchoconstriction (narrowing of bronchioles) initiated by the inhalation of irritating or allergenic agents.

法規制情報

Regulatory Information · 2 件

Chemical: 1,2-Ethanediamine, dihydrochloride

Ethylenediammonium dichloride: Does not have an individual approval but may be used under an appropriate group standard

安全データ

wgk: 2
tsca: TSCA listed
rtecs: KV3850000
毒性: LD50 orally in Rabbit: 3250 mg/kg LD50 dermal Rabbit > 2000 mg/kg
hs_code: 29212100
risk_code: 22-36/37/38-42/43
化審法: (2)-150
hazard_code: Xn
safety_code: 22-26-36/37-45
Hazard Classifications: Acute Tox. 4 OralEye Irrit. 2Resp. Sens. 1Skin Irrit. 2Skin Sens. 1STOT SE 3
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

General Manufacturing Information1,2-Ethanediamine, hydrochloride (1:2): ACTIVE

応用分野 · 2 件

用途金属分析及びキレート剤。

使用Ethylenediamine dihydrochloride is used as stabilizer in steroid creams and rubber latex; inhibitor in antifreeze solutions and cooling fluids; in floor-polish remover; in nystatin cream and aminophylline; epoxy-curing agent; accelerator in color development baths in photography; in veterinary preparations; in electroplating and electrophoretic gels, dyes, fungicides, insecticides, synthetic waxes, textile lubricants, and eye and nose drops; solvent for casein, albumin, shellac.

調製方法

純化方法Crystallise the salt from H2O or H2O/EtOH. Wash the crystals with EtOH and dry them in vacuo. It sublimes on heating. [Beilstein 4 IV 1168.]

上流・下流製品情報

上流原料

エチレンジアミン (無水)塩酸

下流製品

N,N'-ジアクリロイルエチレンジアミン

サプライヤー50 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]

北京华美互利生物化工010-56205725 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

河南萨克斯生物科技有限公司13803717460 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

補足説明

定義ChEBI: A hydrochloride that is the dihydrochloride of ethylenediamine.

エチレンジアミン二塩酸塩

基本情報