トリメチルフルオロシラン

Fluorotrimethylsilane

HCID 9869CAS 420-56-4

基本情報

標準SMILES
C[Si](C)(C)F
InChIKey
CTIKAHQFRQTTAY-UHFFFAOYSA-N
分子式
C3H9FSi
平均分子量
92.19 g/mol
単同位体質量
92.04575504

名称と識別子

優先名称
Fluorotrimethylsilane
IUPAC
fluoro(trimethyl)silane
現地名
トリメチルフルオロシラン
英語名
Trimethylfluorosilane
分子式
C3H9FSi
分子量
92.19

名称と別名

FLUOROTRIMETHYLSILANE420-56-4TrimethylfluorosilaneDTXSID5059959RefChem:899835DTXCID8040014206-997-0fluoro(trimethyl)silaneTrimethylsilyl fluorideSilane, fluorotrimethyl-(CH3)3SiFMFCD00042064
名称をさらに表示
トリメチルシリルフルオリドフルオロトリメチルシラントリメチルフルオロシランfluorotrimethyl-silanSilane,fluorotrimethyl-Trimethylfluorosilane99%Trimethylfluorosilane 99%TRIMETHYLFLUOROSILANE CYL. WITH 100 G
C3H9FSiEINECS 206-997-0Me3SiFTMSFfluoro-trimethyl-silaneFluorotri(methyl)silaneTrimethylsilicon fluorideFluorotrimethylsilane, 96%

データベース識別子

CAS
420-56-4
PubChem CID
9869
DTXSID
DTXSID5059959
EC Number
206-997-0
Nikkaji
J102.055B

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
1
回転可能結合数
0
重原子数
5

実験および物理化学的性質

Chemical ClassesToxic Gases & Vapors -> Fluorosilanes
SpringerMaterials Properties19F nuclear magnetic resonance spectrum
Physical DescriptionLiquefied gas with a pungent irritating odor; [Alfa Aesar MSDS]

物理化学的性質

融点
74 °C · −74 °C(lit.)
沸点
16 °C · 16 °C(lit.)
比重(密度)
0.793 g/mL · 0.793 g/mL at 25 °C(lit.)
闪点
22 °F · −22 °F
溶解性
sol most organic solvents
比重
0.793 · 0.793

化学的性質

化学的特性Clear liquid

安全と法規制

GHS分類

GHS Classification · 4 件

Danger

H224 (100%): Extremely flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards SummaryHydrolyzed by moisture evolving hydrogen fluoride; Causes burns; Inhalation may cause corrosive injuries to the respiratory tract and pulmonary edema; [Alfa Aesar MSDS] See Methyltrifluorosilane and Difluorodimethylsilane.
Hazard Classes and CategoriesFlam. Liq. 1 (100%)

安全と保護具

Exposure Control and Personal Protection · 1 件

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

Protective Action Criteria (PAC) · 3 件

1.0 [ppm]

24 [ppm]

44 [ppm]

毒性情報

Adverse EffectsDermatotoxin - Skin burns.

安全データ

F
4.5-9-21
wgk
3
tsca
TSCA listed
ridadr
UN 1954 2.1
hs_code
2931900090
risk_code
12-36/37/38

化学と産業

用途と製造

General Manufacturing InformationSilane, fluorotrimethyl-: ACTIVE

応用分野

使用Trimethylfluorosilane is used in the pharmaceutical and chemical industry.

調製方法 · 2 件

製造方法Trimethylfluorosilane can be prepared from Chlorotrimethylsilane (TMSCl) by direct treatment with Hydrofluoric Acid. It can also be generated in situ by reaction of Ethyl Trimethylsilylacetate (ETSA) and Tetra-n-butylammonium Fluoride (TBAF).

純化方法It is a FLAMMABLE gas which is purified by fractional distillation through a column at low temperature and with the exclusion of air [Booth & Suttle J Am Chem Soc 68 2658 1946, Reid & Wilkins J Chem Soc 4029 1955]. [Beilstein 4 IV 4007.]

サプライヤー33 社

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関連反応

12 件

関連ノート

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