関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Potassium Acetate | HCID 517044 | — |
| 反応物 | 2,6-Di-tert-butyl-4-(chloromethyl)phenol | HCID 12378601 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | Benzenemethanol, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, 1-acetate | HCID 84404 | 45% |
反応手順
A mixture of 4-chloromethyl-2,6-di-t-butylphenol (2.55 g) and potassium acetate (0.98 g) in acetone (30 mL) was stirred at 20° C. for 24 hours. After evaporation of the solvent the residue was partioned between water and n-hexane. The hexane extract was concentrated and the residue slurried in n-hexane (6 mL) at about 0° C. The crystals were collected via filtration and dried to give 1.54 g, 45% yield, of the title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06048995 |
|---|
| 出典データセット | uspto-grants-2000_04 |
|---|
| ORD ID | ord-c9941dd45f3945949a83a9d18e02784d |
|---|
| 出典メモ | uspto-grants-2000_04 |
|---|
