Trichloroacetonitrile → 3-{4-[2,4-bis(trichloromethyl)-s-triazine-6-yl]phenyl thio}propionic Acid

HRID 1008105

反応式

HRID 1008105 の反応式
[C:1]([C:3]1[CH:8]=[CH:7][C:6]([S:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])=[CH:5][CH:4]=1)#[N:2].[Cl:15][C:16]([Cl:20])([Cl:19])[C:17]#[N:18].[Al](Br)(Br)Br>>[Cl:15][C:16]([Cl:20])([Cl:19])[C:17]1[N:18]=[C:17]([C:16]([Cl:20])([Cl:19])[Cl:15])[N:18]=[C:1]([C:3]2[CH:4]=[CH:5][C:6]([S:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])=[CH:7][CH:8]=2)[N:2]=1

参加物

4

反応物 3

HCID 11011TrichloroacetonitrileHCID 24409Aluminum bromideHCID 226666023-[(4-Cyanophenyl)sulfanyl]propanoic acid

生成物 1

HCID 601112433-{4-[2,4-bis(trichloromethyl)-s-triazine-6-yl]phenyl thio}propionic Acid

反応条件

温度
60 °C

実験手順

The reaction mixture of 22 g of 3-(4-cyanophenyl thio)propionic acid, 150 g of trichloroacetonitrile, and 2 g of AlBr3 was heated to 60° C. in order to dissolve the initially undissolved starting materials, and was bubbled by dry HCl at room temperature.

後処理

  1. dissolutionto dissolve the
  2. customwas bubbled by dry HCl at room temperature

出典と根拠

ORDレコード
ord-55159e626f014794ad064a59718bac78
出典データセット
uspto-grants-2004_09
特許番号
US06797739B1

関連ノート

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