Aluminum(III) Chloride → 4-Iodo-3-nitro-benzophenone

HRID 1017791

反応式

HRID 1017791 の反応式
[I:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=O)=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12].[Cl-].[Cl-].[Cl-].[Al+3]>C1C=CC=CC=1>[I:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([C:2]2[CH:10]=[CH:9][CH:5]=[CH:4][CH:3]=2)=[O:8])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12]

参加物

4

反応物 2

HCID 6451240Aluminum(III) ChlorideHCID 112085984-Iodo-3-nitrobenzoic acid

生成物 1

HCID 111873024-Iodo-3-nitro-benzophenone

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

5.3 g (17 mmol) of 4-iodo-3-nitrobenzoic acid and 8.0 g (60 mmol) of aluminium trichloride are added successively to 70 ml of benzene while cooling with an ice bath. Then the mixture is stirred for 2 hours at ambient temperature, then poured into ice water, extracted with methylene chloride, dried with sodium sulphate and concentrated in vacuo.

後処理

  1. temperaturewhile cooling with an ice bath
  2. extractionextracted with methylene chloride
  3. dry with materialdried with sodium sulphate
  4. concentrationconcentrated in vacuo

出典と根拠

ORDレコード
ord-2af6b35e3597405292621887034b7779
出典データセット
uspto-grants-2002_11
特許番号
US06479524B1

関連ノート

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