Acrylamide → Prop-2-enamide;styrene

HRID 1018397ノート

反応式

HRID 1018397 の反応式
[Cl-].C[N+](C)(C)CCOC(=O)C=C.[CH2:13]=[CH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[C:21]([NH2:25])(=[O:24])[CH:22]=[CH2:23]>C(O)(C)C>[CH2:13]=[CH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[C:21]([NH2:25])(=[O:24])[CH:22]=[CH2:23]

参加物

5

反応物 3

HCID 6579AcrylamideHCID 7501StyreneHCID 162071Ethanaminium, N,N,N-trimethyl-2-[(1-oxo-2-propen-1-yl)oxy]-, chloride (1:1)

生成物 1

HCID 168235Prop-2-enamide;styrene

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

反応条件

温度
75 °C

実験手順

To a 500 mL round-bottom, three-neck flask fitted with a thermocouple, reflux condenser, and septum was added 150 ml, of isopropanol followed by 16.13 g of a 50% aqueous solution of 2-trimethylammonioethylacrylate chloride, 8.06 g of styrene, and 8.06 g of acrylamide. The solution was purged with nitrogen for 1 hour and 0.5 g AIBN was added. The mixture was purged for ˜15 minutes until all of the AIBN dissolved. The solution was heated to 75° C. under nitrogen for 16 hours.

後処理

  1. customTo a 500 mL round-bottom, three-neck flask fitted with a thermocouple
  2. temperaturereflux condenser
  3. additionseptum was added 150 ml
  4. customThe solution was purged with nitrogen for 1 hour
  5. addition0.5 g AIBN was added
  6. customThe mixture was purged for ˜15 minutes until all of the AIBN
  7. dissolutiondissolved

出典と根拠

ORDレコード
ord-61925649456f401e87e2225b135a8fbd
出典データセット
uspto-grants-2002_11
特許番号
US06482402B1

反応ノート

読み込み中…