Bisphenol A → Phosphoric acid, P,P'-((1-methylethylidene)di-4,1-phenylene) P,P,P',P'-tetraphenyl ester
反応式
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:11]2[CH:16]=[CH:15][C:14]([OH:17])=[CH:13][CH:12]=2)([CH3:10])[CH3:9])=[CH:4][CH:3]=1.[P:18](Cl)([O:27][C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)([O:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)=[O:19]>N1C=CC=CC=1>[CH3:9][C:8]([C:11]1[CH:12]=[CH:13][C:14]([O:17][P:18]([O:20][C:21]2[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=2)([O:27][C:28]2[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=2)=[O:19])=[CH:15][CH:16]=1)([C:5]1[CH:4]=[CH:3][C:2]([O:1][P:18]([O:27][C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)([O:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[O:19])=[CH:7][CH:6]=1)[CH3:10]参加物
4
実験手順
Bisphenol A bis(diphenyl phosphate) was prepared by the reaction of 11.4 g of bisphenol A with 29.6 g of diphenyl chlorophosphate in 100 ml of pyridine, which was performed by the protocol of Example 2. Recrystallization from isopropanol gave 12 g of the title compound of mp=56°-58° C. Mass spectrum: m/e 692. Elemental analysis found weight percent C=68.2 and weight percent H=5.04.