Hydrogen Sulfide → 3,5-Di-tert-butyl-4-hydroxyphenyl dithiocarbamate

HRID 1030225ノート

反応式

HRID 1030225 の反応式
[C:1]([C:5]1[CH:6]=[C:7]([S:16][C:17]#[N:18])[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])([CH3:4])([CH3:3])[CH3:2].C(N(CC)CC)C.[SH2:26]>C(OCC)C>[C:17](=[S:26])([S:16][C:7]1[CH:6]=[C:5]([C:1]([CH3:4])([CH3:2])[CH3:3])[C:10]([OH:11])=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[CH:8]=1)[NH2:18]

参加物

5

反応物 3

HCID 402Hydrogen SulfideHCID 8471TriethylamineHCID 6192452,6-DI-Tert-butyl-4-thiocyanato-phenol

生成物 1

HCID 198222993,5-Di-tert-butyl-4-hydroxyphenyl dithiocarbamate

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

3,5-Di-tert-butyl-4-hydroxyphenyl thiocyanate (8.7 g) and 0.3 g of triethylamine were dissolved in 80 ml of diethyl ether, and hydrogen sulfide was blown into the solution at room temperature over 4.5 hours. The reaction mixture was concentrated, and the crude product thus obtained was washed with diethyl ether to give 7.5 g of the desired compound as a colorless solid.

後処理

  1. concentrationThe reaction mixture was concentrated
  2. customthe crude product thus obtained
  3. washwas washed with diethyl ether

出典と根拠

ORDレコード
ord-f36eeb5821fc47d0bea9d53a851b063b
出典データセット
uspto-grants-1992_04
特許番号
US05104889

反応ノート

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