Carbon Disulfide → HCID 178446353、化合物

HRID 1032865

反応式

HRID 1032865 の反応式
[OH-].[Na+].[CH2:3]([NH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:4][CH2:5][CH2:6][CH3:7].[C:14](=[S:16])=[S:15].[W:17](Cl)(Cl)(Cl)(Cl)(Cl)Cl>CO>[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[W+6:17]

参加物

6

反応物 4

HCID 6348Carbon DisulfideHCID 14798Sodium HydroxideHCID 16316DipentylamineHCID 83301Tungsten hexachloride

生成物 1

HCID 178446353HCID 178446353、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒2 回

実験手順

0.576 kg of granulated caustic soda is added to 8 liters of anhydrous methanol and the mixture is stirred until all solid material has dissolved. 2.26 kg of diamylamine are added to the solution and 0.88 liter of carbon disulfide is introduced over a period of 2 hours. The mixture is stirred for a further 3 hours at 25° C. and a solution of 0.952 kg of tungsten hexachloride in 2.4 liters of anhydrous methanol is then added over a period of one hour and the mixture is stirred for an additional 3 hours.

後処理

  1. dissolutionhas dissolved
  2. additionis introduced over a period of 2 hours
  3. stirringThe mixture is stirred for a further 3 hours at 25° C.
  4. stirringthe mixture is stirred for an additional 3 hours

出典と根拠

ORDレコード
ord-509824005bfb4f039a021a270549f27e
出典データセット
uspto-grants-1994_05
特許番号
US05308519

関連ノート

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