Potassium thiocyanate → HCID 19024929、化合物
反応式
[CH3:1][O:2][CH2:3][C:4]1([CH2:7][O:8][CH3:9])[CH2:6]O1.[S-:10]C#N.[K+]>O>[CH3:1][O:2][CH2:3][C:4]1([CH2:7][O:8][CH3:9])[CH2:6][S:10]1参加物
4
実験手順
2,2-Bis(methoxymethyl)oxirane (13 g) was stirred with a solution of potassium thiocyanate (9.7 g) in water (40 cm3) for 18 h at room temperature. The aqueous layer was then replaced with a fresh solution of potassium thiocyanate (9.7 g) in water (40 cm3) and the mixture stirred for a further 6 h. The bulk of the thiirane was then separated from the aqueous layer which was then extracted with diethyl ether. These extracts were combined with the bulk of the thiirane, the solution dried and the solvent removed (40° C. at 15 mmHg) to give the thiirane (13 g, 90%) as a colourless liquid.
後処理
- customThe bulk of the thiirane was then separated from the aqueous layer which
- extractionwas then extracted with diethyl ether
- customthe solution dried
- customthe solvent removed (40° C. at 15 mmHg)
出典と根拠
- ORDレコード
- ord-449b25f97cbe48d2abae209d75a5d376
- 出典データセット
- uspto-grants-1994_05
- 特許番号
- US05312904
反応ノート
読み込み中…