Sodium Nitrate → HCID 178524577、化合物

HRID 1038451ノート

反応式

HRID 1038451 の反応式
[OH:1][C:2]1[N:10]=[CH:9][CH:8]=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].[N+:11]([O-])([O-:13])=[O:12].[Na+]>S(=O)(=O)(O)O>[OH:1][C:2]1[N:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5]

参加物

4

反応物 2

HCID 24268Sodium NitrateHCID 178418543HCID 178418543、化合物

生成物 1

HCID 178524577HCID 178524577、化合物収率 45%

試薬・触媒・溶媒 1

HCID 1118Sulfuric Acid溶媒

実験手順

To 2-hydroxy-nicotinic acid (3.6 mmol) in sulfuric acid (30% free SO3, 2 ml) was added sodium nitrate (7.2 mmol) portionwise over 20 min. The solution was allowed to stir for 20 h at room temperature. The solution was then poured onto ice-water and the precipitate that formed was filtered off, washed with water and dried in a vacuum oven to afford a pale yellow solid (45%).

後処理

  1. additionThe solution was then poured onto ice-water
  2. customthe precipitate that formed
  3. filtrationwas filtered off
  4. washwashed with water
  5. customdried in a vacuum oven

出典と根拠

ORDレコード
ord-e2ae3eed7f2c495eade4da86094b2e78
出典データセット
uspto-grants-2013_10
特許番号
US08551990B2

反応ノート

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