1-Methylimidazole → HCID 86647249、化合物

HRID 1043394ノート

反応式

HRID 1043394 の反応式
[CH3:1][N:2]1[CH:6]=[CH:5][N:4]=[CH:3]1.[I:7][CH2:8][CH2:9][CH2:10][Si:11]([O:16][CH3:17])([O:14][CH3:15])[O:12][CH3:13]>>[I-:7].[CH3:1][N+:2]1[CH:6]=[CH:5][N:4]([CH2:8][CH2:9][CH2:10][Si:11]([O:16][CH3:17])([O:14][CH3:15])[O:12][CH3:13])[CH:3]=1

参加物

3

反応物 2

HCID 13901-MethylimidazoleHCID 2759373(3-Iodopropyl)trimethoxysilane

生成物 1

HCID 86647249HCID 86647249、化合物

反応条件

温度
114 °C

実験手順

N-Methylimidazole (156.8 g; 1.91 mol) and 3-iodopropyltrimethoxysilane (569.8 g; 1.96 mol) were charged to a 1 L, 3-necked flask to form a reaction mixture. The reaction mixture was heated to 114° C. for eight hours during which time the color of the mixture changed from pale yellow to green and then to black. The crude reaction product was washed twice with 80 mL of toluene (2×40 mL). The resulting black oily liquid of N-methyl-N′-(3-trimethoxysilylpropyl) imidazolium iodide was dissolved in 286 g of methylene chloride and maintained as a solution.

後処理

  1. customto form a reaction mixture
  2. customThe crude reaction product
  3. washwas washed twice with 80 mL of toluene (2×40 mL)
  4. dissolutionThe resulting black oily liquid of N-methyl-N′-(3-trimethoxysilylpropyl) imidazolium iodide was dissolved in 286 g of methylene chloride
  5. temperaturemaintained as a solution

出典と根拠

ORDレコード
ord-42adac45bab34de1a98c8045eb286cf2
出典データセット
uspto-grants-2013_10
特許番号
US08563459B2

反応ノート

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