Trifluoroacetic acid → 3,4-Bis(methylsulfonyl)benzoic acid
反応式
C([O:5][C:6](=[O:21])[C:7]1[CH:12]=[CH:11][C:10]([S:13]([CH3:16])(=[O:15])=[O:14])=[C:9]([S:17]([CH3:20])(=[O:19])=[O:18])[CH:8]=1)(C)(C)C.FC(F)(F)C(O)=O>ClCCl>[CH3:20][S:17]([C:9]1[CH:8]=[C:7]([CH:12]=[CH:11][C:10]=1[S:13]([CH3:16])(=[O:15])=[O:14])[C:6]([OH:21])=[O:5])(=[O:19])=[O:18]参加物
4
実験手順
To 3,4-bis-methanesulfonyl-benzoic acid tert-butyl ester (0.366 g) in dichloromethane was added trifluoroacetic acid and the reaction mixture was stirred for 3 hours. The mixture was evaporated and trituration of the residue with diethyl ether gave the title compound (0.29 g; MS: APCI+(M+H) 279).
後処理
- customThe mixture was evaporated
出典と根拠
- ORDレコード
- ord-438397359b0349789d0c29fcb3dddf15
- 出典データセット
- uspto-grants-2003_02
- 特許番号
- US06525070B2
反応ノート
読み込み中…