Propan-2-yl 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propanoate → (CF3)2Cfococf(CF3)ocf2CF2CF3

HRID 1064557

反応式

HRID 1064557 の反応式
C(OC(C(OC(C(C(F)(F)F)(F)F)(F)F)(C(F)(F)F)[F:8])=O)(C)C.[CH:24]([O:33][C:34]([C:36]([O:42][C:43]([C:46]([C:49]([F:52])([F:51])[F:50])([F:48])[F:47])([F:45])[F:44])([C:38]([F:41])([F:40])[F:39])[F:37])=[O:35])([C:29]([F:32])([F:31])[F:30])[C:25]([F:28])([F:27])[F:26]>C1C=CC=CC=1>[C:24]([O:33][C:34]([C:36]([O:42][C:43]([C:46]([C:49]([F:50])([F:51])[F:52])([F:48])[F:47])([F:44])[F:45])([C:38]([F:40])([F:39])[F:41])[F:37])=[O:35])([C:29]([F:32])([F:31])[F:30])([C:25]([F:28])([F:27])[F:26])[F:8]

参加物

4

反応物 2

HCID 10177266Propan-2-yl 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propanoate2 回HCID 10277469(CF3)2Chococf(CF3)ocf2CF2CF3

生成物 1

HCID 131724614(CF3)2Cfococf(CF3)ocf2CF2CF3

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

Further, the same operation was repeated once. The total amount of benzene injected was 0.219 g, and the total amount of R-113 injected was 21 ml. Further, nitrogen was supplied for 1.5 hours. The product was quantified by 19F-NMR, whereby the yield of the above identified compound to (CH3)2CHOCOCF(CF3)OCF2CF2CF3, was 48.1%, and the yield of (CF3)2CHOCOCF(CF3)OCF2CF2CF3 to (CH3)2CHOCOCF(CF3)OCF2CF2CF3, was 19.1%.

出典と根拠

ORDレコード
ord-b79f83f57f5546bc90cfd9bd875c024e
出典データセット
uspto-grants-2005_11
特許番号
US06969776B2

関連ノート

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