4-Aminophenol → Phenolindophenol

HRID 1065595

反応式

HRID 1065595 の反応式
[NH2:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1.C[C:10]1[CH:15]=[CH:14][C:13](N)=[C:12]([N+]([O-])=O)[C:11]=1[OH:20].S(OOS([O-])(=O)=O)([O-])(=O)=O.[NH4+].[NH4+]>N.O>[CH:7]1[C:2](=[N:1][C:14]2[CH:13]=[CH:12][C:11]([OH:20])=[CH:10][CH:15]=2)[CH:3]=[CH:4][C:5](=[O:8])[CH:6]=1

参加物

6

反応物 3

HCID 4034-AminophenolHCID 62648Ammonium PersulfateHCID 193893123-Amino-6-methyl-2-nitrophenol

生成物 1

HCID 10379Phenolindophenol

試薬・触媒・溶媒 2

HCID 222Ammonia溶媒HCID 962Water溶媒2 回

反応条件

温度
0 °C

実験手順

0.01 mole (1.09 g) of para-amino-phenol and 0.01 mole (1.68 g) of 2-methyl-5-amino-6-nitro phenol are dissolved in 15 cc of ammonia (22° Be) to which have been added 15 cc of water. To this resulting solution maintained at a temperature of about 0° C., there is added, with agitation, 0.02 mole (4.6 g) of ammonium persulfate in 20 cc of water. The agitation is maintained for 30 minutes, after which the indophenol which has precipitated in the form of its ammonium salt is filtered. The thus recovered crude product is treated with water to which has been added acetic acid to obtain the indophenol in its free form. After filtering the indophenol, washing it with water and drying it under a vacuum, there is obtained a product which melts with decomposition above 260° C.

後処理

  1. temperatureThe agitation is maintained for 30 minutes
  2. customafter which the indophenol which has precipitated in the form of its ammonium salt
  3. filtrationis filtered
  4. customThe thus recovered crude product
  5. additionis treated with water to which
  6. additionhas been added acetic acid

出典と根拠

ORDレコード
ord-e1191c09127047298e5ef2d0c66e260c
出典データセット
uspto-grants-1982_05
特許番号
US04330291

関連ノート

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