Pentachlorophenol → Oxine-copper

HRID 1065959

反応式

HRID 1065959 の反応式
[CH3:1][N:2]([CH3:12])C(=S)SSC(=S)N(C)C.[CH:13]1C=C2[C:16]([CH:17]=[C:18]([C:23]([O-])=[O:24])C=C2)=[CH:15][CH:14]=1.[CH:26]1C=C2[C:29]([CH:30]=[C:31]([C:36]([O-])=[O:37])C=C2)=[CH:28][CH:27]=1.[Cu+2:39].ClC1C(O)=C(Cl)C(Cl)=C(Cl)C=1Cl.O([As]1C2C=CC=CC=2OC2C1=CC=CC=2)[As]1C2C=CC=CC=2OC2C1=CC=CC=2.C1C(Cl)=C(Br)C=C2OC(NC=12)=O.C([O-])(=O)/C=C\C([O-])=O.C([Sn+2](CCCC)CCCC)CCC>>[N:2]1[C:12]2[C:15](=[CH:16][CH:17]=[CH:18][C:23]=2[O-:24])[CH:14]=[CH:13][CH:1]=1.[Cu+2:39].[N:2]1[C:12]2[C:28](=[CH:29][CH:30]=[CH:31][C:36]=2[O-:37])[CH:27]=[CH:26][CH:1]=1

参加物

7

反応物 6

HCID 992Pentachlorophenol2 回HCID 5455ThiramHCID 601710,10'-OxybisphenoxarsineHCID 21749BromchlorenoneHCID 15607801Copper(2+) bis(2-naphthoate)HCID 178448211HCID 178448211、化合物

生成物 1

HCID 3032555Oxine-copper

実験手順

mercaptan (0.2-4%, in, e.g., vinyl); tetramethylthiuram disulfide (0.4-4%, in, e.g., vinyl or cellulose nitrate); copper napthenate (0.2-4% in, e.g., PVC or PVA); pentachlorophenol (1-20%, in, e.g., lacquer or cellulose nitrate); phenyl mercuric formate (0.05-10%, in, e.g., nylon); pentachlorophenol (0.2-4%, in, e.g., celluose nitrate); 10,10′-oxybisphenoxarsine (OBPA) (0.005-2%, in a variety of plastics, including vinyl, PVC, and others; sometime sold under trade names, “Intercide” or Vinyzene); organotins (0.005-2%, in, e.g., PVC) (examples of organotins are, e.g., bis (tri-n-butyltin)sulfosalicylate (0.25-0.5% of plasticizer, used in e.g., PVC), or the preferred tri-n-butyltin maleate (0.005-1%, in, e.g., urethanes, paint-compounds); brominated salicylanilide (0.04-1%, in, e.g., polyethylene).

出典と根拠

ORDレコード
ord-84e6ca701a5d48cb95605b0cce7d507d
出典データセット
uspto-grants-2001_06
特許番号
US06240879B1

関連ノート

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