1-Methylimidazole → 1,3-dimethylimidazolium tetrafluoroborate

HRID 1067041ノート

反応式

HRID 1067041 の反応式
[F:1][B-:2]([F:5])([F:4])[F:3].[CH3:6][O+](C)C.[CH3:10][N:11]1[CH:15]=[CH:14][N:13]=[CH:12]1>ClCCCl>[F:1][B-:2]([F:5])([F:4])[F:3].[CH3:10][N+:11]1[CH:15]=[CH:14][N:13]([CH3:6])[CH:12]=1

参加物

4

反応物 2

HCID 13901-MethylimidazoleHCID 2735153Oxonium, trimethyl-, tetrafluoroborate(1-) (1:1)

生成物 1

HCID 112061841,3-dimethylimidazolium tetrafluoroborate

試薬・触媒・溶媒 1

HCID 111,2-Dichloroethane溶媒2 回

実験手順

The procedure of Example 2 was followed. 3.9 g of trimethyloxonium tetrafluoroborate in suspension in 20 ml of 1,2-dichloroethane was added to 2.1 ml (2.16 g) of N-methylimidazole in 5 ml of 1,2-dichloroethane. The mixture was stirred for 4 hours at room temperature. A salt was formed (lower phase) which was non miscible with the solvent and was separated by decanting. The remaining solvent was evaporated off under vacuum using a vane pump. A colorless liquid was obtained.

後処理

  1. customA salt was formed (lower phase) which
  2. customwas separated
  3. customby decanting
  4. customThe remaining solvent was evaporated off under vacuum
  5. customA colorless liquid was obtained

出典と根拠

ORDレコード
ord-62db98ef5b714b1d872d3a431d9eb287
出典データセット
uspto-grants-2001_06
特許番号
US06245918B1

反応ノート

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