HCID 20496709、化合物 → HCID 20496693、化合物
反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][OH:16])=[CH:6][CH:5]=1)([O-])=O>[Pd].C(O)C>[NH2:1][C:4]1[CH:5]=[CH:6][C:7]([CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][OH:16])=[CH:8][CH:9]=1参加物
4
実験手順
A solution was prepared from 8.5 g of 6-(4-nitrophenyl)hexanol and 150 ml of ethanol and 0.42 g of 10% Pd/C catalyst was added. The resulting mixture was shaken under hydrogen (2.7-3.3 atmospheres) at room temperature for 2 hours. The catalyst was then removed by filtration and the solvent was evaporated from the filtrate to leave a crude tan solid. The solid was recrystallized from ethyl acetate/hexane to give 6-(4-aminophenyl)hexanol.
後処理
- additionwas added
- customThe catalyst was then removed by filtration
- customthe solvent was evaporated from the filtrate
- customto leave a crude tan solid
- customThe solid was recrystallized from ethyl acetate/hexane
出典と根拠
- ORDレコード
- ord-d313ee34a0984847b93b397f148dec61
- 出典データセット
- uspto-grants-1983_07
- 特許番号
- US04391818
反応ノート
読み込み中…