Aluminum Stearate → Ethylene brassylate

HRID 1074626

反応式

HRID 1074626 の反応式
[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13]CCCCC.[Al+3].[C:22]([O-])(=[O:40])[CH2:23]CCCCCCCCCCCCCCCC.C([O-])(=[O:60])CCCCCCCCCCCCCCCCC.C([O-])(=O)CCCCCCCCCCCCCCCCC.[Na+]>C([O-])(=O)CCCCCCCCCCCCCCCCC.[Al+3].C([O-])(=O)CCCCCCCCCCCCCCCCC.C([O-])(=O)CCCCCCCCCCCCCCCCC.C([O-])(=O)CCCCCCCCCCCCCCCCC.[Pb+2].C([O-])(=O)CCCCCCCCCCCCCCCCC>[C:13]1(=[O:60])[O:40][CH2:22][CH2:23][O:20][C:1](=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]1

参加物

5

反応物 2

HCID 12496Aluminum StearateHCID 2724691Sodium Stearate

生成物 1

HCID 61014Ethylene brassylate収率 95.9%

試薬・触媒・溶媒 2

HCID 12496Aluminum Stearate触媒HCID 61258Lead stearate触媒

実験手順

To demonstrate the improved yields and increased reaction rates obtained utilizing the mixed metal catalysts of this invention, batch polymerizations were identically conducted using (a) a mixed metal catalyst comprised of aluminum stearate and sodium stearate (1:1 molar ratio), (b) aluminum stearate catalyst, and (c) lead stearate catalyst. These reactions were conducted in accordance with the procedure employed in Example II utilizing 74 grams poly(ethylene brassylate) and 0.5 mole percent of the catalyst. Reactions were carried out at 310°-320° C. and 0.1-0.5 mm Hg. for four hours. The amount of distillate (crude ethylene brassylate) recovered was recorded after the first hour of reaction. With the mixed metal catalyst, 45 mls. ethylene brassylate was obtained after 1 hour and the overall yield was 95.9%. With the aluminum stearate, 36 mls. crude ethylene brassylate was obtained in the first hour and the overall yield was only 78%. Using lead stearate only 25 mls distillate was obtained after 1 hour and the yield of crude ethylene brassylate was 69.1%.

後処理

  1. customimproved yields
  2. temperatureincreased
  3. customreaction rates
  4. customobtained
  5. customwere carried out at 310°-320° C.
  6. distillationThe amount of distillate (crude ethylene brassylate) recovered
  7. customafter the first hour of reaction

出典と根拠

ORDレコード
ord-3d21785902354b2ebab564dc16dbe394
出典データセット
uspto-grants-1983_07
特許番号
US04393223

関連ノート

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