Methylhydroquinone → Methyl-1,4-benzoquinone

HRID 1074900

反応式

HRID 1074900 の反応式
[CH3:1][C:2]1[CH:8]=[C:7]([OH:9])[CH:6]=[CH:5][C:3]=1[OH:4].Cl[O-]>C(Cl)(Cl)Cl>[CH3:1][C:2]1[C:3](=[O:4])[CH:5]=[CH:6][C:7](=[O:9])[CH:8]=1

参加物

4

反応物 2

HCID 7253MethylhydroquinoneHCID 61739Hypochlorite

生成物 1

HCID 11122Methyl-1,4-benzoquinone

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

2-methyl hydroquinone (1b) of 3.0 g (24 mmol) is dissolved in 150 ml of chloroform, wherein 100 ml each of hypochloride solution which have been so prepared as mentioned above are added and each reaction is made in the same way as described in Example 1, and then 2-methyl benzoquinone (IIb) is obtained. Table below shows the yields of isolation corresponding to each case of the investigation:

後処理

  1. additionabove are added

出典と根拠

ORDレコード
ord-054885253cbc4b59beba4cc150ab1079
出典データセット
uspto-grants-1983_07
特許番号
US04394315

関連ノート

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