Trichloroethylene → 2-METHYL-4,5,alpha,beta-TETRACHLOROSTYRENE
反応式
[Cl:1][CH:2]=[C:3](Cl)[Cl:4].[Cl:6][C:7]1[CH:8]=[C:9]([CH3:14])[CH:10]=[CH:11][C:12]=1[Cl:13].[Cl-].[Al+3].[Cl-].[Cl-]>>[CH3:14][C:9]1[CH:8]=[C:7]([Cl:6])[C:12]([Cl:13])=[CH:11][C:10]=1[C:3]([Cl:4])=[CH:2][Cl:1]参加物
4
実験手順
A mixture containing 131.5 g (1.0 mole), of trichloroethylene, 80.5 (0.5 mole) of 3,4-dichlorotoluene and 5 g. of aluminum chloride was stirred and heated at reflux for 2 hours. The reaction mixture was then washed with concentrated HCl, then with water until neutral, dried and distilled. 42.7 grams of product was collected, having a boiling point of 97°-102°C at 0.5 mm Hg pressure.
後処理
- additionA mixture containing 131.5 g (1.0 mole)
- temperatureheated
- temperatureat reflux for 2 hours
- washThe reaction mixture was then washed with concentrated HCl
- dry with materialwith water until neutral, dried
- distillationdistilled
- custom42.7 grams of product was collected
出典と根拠
- ORDレコード
- ord-d4be8981b50d4d08a51b74a624717a0e
- 出典データセット
- uspto-grants-1976_05
- 特許番号
- US03957891
反応ノート
読み込み中…