4-Chlorophenyl Isocyanate → methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate

HRID 1077070

反応式

HRID 1077070 の反応式
[NH2:1][C:2](=[N:5][C:6](=[O:9])[O:7][CH3:8])[O:3][CH3:4].NC(=NC(=O)OC)SC.[Cl:19][C:20]1[CH:25]=[CH:24][C:23]([N:26]=[C:27]=[O:28])=[CH:22][CH:21]=1>C(Cl)Cl>[Cl:19][C:20]1[CH:25]=[CH:24][C:23]([NH:26][C:27](=[O:28])[NH:1][C:2](=[N:5][C:6]([O:7][CH3:8])=[O:9])[O:3][CH3:4])=[CH:22][CH:21]=1

参加物

5

反応物 3

HCID 76934-Chlorophenyl IsocyanateHCID 2935781-methoxycarbonyl-S-methylisothioureaHCID 53429793N-carbomethoxy-O-methylisourea

生成物 1

HCID 54018948methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

To 13 parts of methyl N-(1-amino-1-methoxymethylene)carbamate, m.p. 36°-39.5°, prepared similar to the procedure in Example 3 for methyl N-(1-amino-1-methylthiomethylene)carbamate in 140 parts of methylene chloride is added 15 parts of p-chlorophenyl isocyanate. The reaction mixture is stirred overnight and the solution filtered to give 10 parts of methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate melting at 170° dec.

後処理

  1. filtrationthe solution filtered

出典と根拠

ORDレコード
ord-37e59f04e23c4b9a8f647ce3abf416da
出典データセット
uspto-grants-1976_05
特許番号
US03959331

関連ノート

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