Methyl iodide → trans-3-(3-(2-Hexenyloxy)-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide

HRID 1077765ノート

反応式

HRID 1077765 の反応式
[CH3:1][I:2].[CH2:3]([O:9][C:10]1[C:14]([C:15]2[CH:16]=[N:17][CH:18]=[CH:19][CH:20]=2)=[N:13][S:12][N:11]=1)/[CH:4]=[CH:5]/[CH2:6][CH2:7][CH3:8]>CC(C)=O>[I-:2].[CH2:3]([O:9][C:10]1[C:14]([C:15]2[CH:16]=[N+:17]([CH3:1])[CH:18]=[CH:19][CH:20]=2)=[N:13][S:12][N:11]=1)/[CH:4]=[CH:5]/[CH2:6][CH2:7][CH3:8]

参加物

4

反応物 2

HCID 6328Methyl iodideHCID 19075257trans-3-(3-(2-Hexenyloxy)-1,2,5-thiadiazol-4-yl)pyridine

生成物 1

HCID 19075386trans-3-(3-(2-Hexenyloxy)-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

A mixture of methyl iodide (0.5 ml, 7.5 mmol) and trans-3-(3-(2-hexenyloxy)-1,2,5-thiadiazol-4-yl)pyridine (3 mmol) in acetone (5 ml) was stirred at room temperature for 18 h. The title compound precipitated from the solution and was collected by filtration to yield 1.09 g (90%).

後処理

  1. customThe title compound precipitated from the solution
  2. filtrationwas collected by filtration
  3. customto yield 1.09 g (90%)

出典と根拠

ORDレコード
ord-55cb581878dd457ebab12487a2d92260
出典データセット
uspto-grants-1996_08
特許番号
US05545638

反応ノート

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