Phenyltrichlorosilane → Dichlorodiphenylsilane

HRID 1078002

反応式

HRID 1078002 の反応式
C(N([CH2:6][CH3:7])CC)C.[C:8]1([Si:14]([Cl:17])([Cl:16])Cl)[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>C1([SiH](Cl)Cl)C=CC=CC=1.C1C=CC=CC=1>[C:8]1([Si:14]([C:7]2[CH:6]=[CH:10][CH:9]=[CH:8][CH:13]=2)([Cl:16])[Cl:17])[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1

参加物

5

反応物 2

HCID 7372PhenyltrichlorosilaneHCID 8471Triethylamine

生成物 1

HCID 6627Dichlorodiphenylsilane収率 253.1%

試薬・触媒・溶媒 2

HCID 74207Dichloro(phenyl)silane触媒HCID 241Benzene溶媒

実験手順

Triethylamine (3.9 g) was added to a flask containing 83.3 g of the crude product mixture described in Example 1. This mixture was stripped by the process described in Example 1. The volatiles were condensed and analyzed by GC-TCD. About 77.4 g of a liquid was recovered comprising 24.7 g of diphenyldichlorosilane (yield of 77 percent), 1.4 g of phenyldichlorosilane, 24.5 g of phenyltrichlorosilane, and 10.1 g of benzene.

後処理

  1. customcondensed
  2. customAbout 77.4 g of a liquid was recovered

出典と根拠

ORDレコード
ord-7290619a4c9d4a31a80dd0728247d398
出典データセット
uspto-grants-1996_08
特許番号
US05545743

関連ノート

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