Benzyl acetate → 7-Ethyl-1-hydroxy-12-[2'-(4"-hydroxy-4"-[benzyloxycarbonylmethyl]-3"-methoxycyclohexyl)-1'-methylvinyl]-14-tert-butyldimethylsilyloxy-23,25-dimethoxy-13,19,21,27-tetramethyl-11,28-dioxa-4-azatricyclo[22.3.1.04,9]octacos-18-ene-2,3,10,16-tetraone

反応式

[CH3:1][C:2]1C(C)=C(C)[SiH](C)[SiH-](C)(C)C=1.[Na+].[C:14]([O:17][CH2:18][C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)(=[O:16])[CH3:15].C([CH:27]1[CH:53]=[C:52]([CH3:54])[CH2:51][CH:50]([CH3:55])[CH2:49][CH:48]([O:56][CH3:57])[CH:47]2[O:58][C:43]([OH:62])([CH:44]([CH3:61])[CH2:45][CH:46]2[O:59][CH3:60])[C:42](=[O:63])[C:41](=[O:64])[N:40]2[CH:35]([CH2:36][CH2:37][CH2:38][CH2:39]2)[C:34](=[O:65])[O:33][CH:32]([C:66]([CH3:77])=[CH:67][CH:68]2[CH2:73][CH2:72][C:71](=[O:74])[CH:70]([O:75][CH3:76])[CH2:69]2)[CH:31]([CH3:78])[CH:30]([O:79][Si:80]([C:83]([CH3:86])([CH3:85])[CH3:84])([CH3:82])[CH3:81])[CH2:29][C:28]1=[O:87])C>O1CCCC1>[CH2:1]([CH:37]1[CH2:36][CH:35]2[N:40]([C:41](=[O:64])[C:42](=[O:63])[C:43]3([OH:62])[O:58][CH:47]([CH:48]([O:56][CH3:57])[CH2:49][CH:50]([CH3:55])[CH2:51][C:52]([CH3:54])=[CH:53][CH2:27][C:28](=[O:87])[CH2:29][CH:30]([O:79][Si:80]([C:83]([CH3:84])([CH3:85])[CH3:86])([CH3:82])[CH3:81])[CH:31]([CH3:78])[CH:32]([C:66]([CH3:77])=[CH:67][CH:68]4[CH2:73][CH2:72][C:71]([OH:74])([CH2:15][C:14]([O:17][CH2:18][C:19]5[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=5)=[O:16])[CH:70]([O:75][CH3:76])[CH2:69]4)[O:33][C:34]2=[O:65])[CH:46]([O:59][CH3:60])[CH2:45][CH:44]3[CH3:61])[CH2:39][CH2:38]1)[CH3:2]