Diisopropyl Ether → HCID 15839966、化合物

反応式

[O:1]([CH:8]([CH:12]([CH3:14])[CH3:13])[C:9]([OH:11])=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N+]([O-])(O)=O.[O:19]([CH2:23][CH2:24][NH2:25])[N+:20]([O-:22])=[O:21].C(OC(C)C)(C)C>>[O:19]([CH2:23][CH2:24][NH:25][C:9](=[O:11])[CH:8]([O:1][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1)[CH:12]([CH3:14])[CH3:13])[N+:20]([O-:22])=[O:21]

参加物

反応物 3

HCID 7914Diisopropyl Ether

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)

HCID 35186033-Methyl-2-phenoxybutanoic acid

生成物 1

HCID 15839966HCID 15839966、化合物収率 68.9%

実験手順

Following a similar treatment to that in Example 2 and using 0.47 g of 2-phenoxy-3-methylbutyric acid and 0.40 g of 2-nitroxyethylamine nitrate, 0.46 g of the title compound was obtained as colorless powdery crystals (solvent for recrystallization; diisopropyl ether).

出典と根拠

ORDレコード: ord-5285f85e3dac473296d49ecce130b116
出典データセット: uspto-grants-1996_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05580893

反応ノート

読み込み中…