1-(3-Bromopropoxy)-3-nitrobenzene → 3-(3-Bromopropoxy)-aniline

HRID 1086930

反応式

HRID 1086930 の反応式
[Br:1][CH2:2][CH2:3][CH2:4][O:5][C:6]1[CH:7]=[C:8]([N+:12]([O-])=O)[CH:9]=[CH:10][CH:11]=1>[Ni].O1CCCC1>[Br:1][CH2:2][CH2:3][CH2:4][O:5][C:6]1[CH:7]=[C:8]([CH:9]=[CH:10][CH:11]=1)[NH2:12]

参加物

4

反応物 1

HCID 71723011-(3-Bromopropoxy)-3-nitrobenzene

生成物 1

HCID 4592563-(3-Bromopropoxy)-aniline

試薬・触媒・溶媒 2

HCID 935Nickel触媒HCID 8028Tetrahydrofuran溶媒

実験手順

1 g of Raney nickel is added to a solution of 4 g of 3-(3-bromopropoxy)-nitrobenzene in 40 ml of tetrahydrofuran and the starting substance is hydrogenated at room temperature. The catalyst is filtered off and washed with tetrahydrofuran. Evaporation of the filtrate gives 3-(3-bromopropoxy)-aniline as a colourless oil.

後処理

  1. customis hydrogenated at room temperature
  2. filtrationThe catalyst is filtered off
  3. washwashed with tetrahydrofuran
  4. customEvaporation of the filtrate

出典と根拠

ORDレコード
ord-c1aef05df36f4eddbfc246c470a9fab0
出典データセット
uspto-grants-1991_07
特許番号
US05032606

関連ノート

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