Nitric Acid → 4,4'-Dichlorobenzophenone

HRID 1088002

反応式

HRID 1088002 の反応式
ClC(Cl)=[C:3]([C:11]1[CH:16]=[CH:15][C:14]([Cl:17])=[CH:13][CH:12]=1)[C:4]1[CH:9]=[CH:8][C:7]([Cl:10])=[CH:6][CH:5]=1.[N+]([O-])(O)=[O:20]>O>[Cl:10][C:7]1[CH:8]=[CH:9][C:4]([C:3]([C:11]2[CH:16]=[CH:15][C:14]([Cl:17])=[CH:13][CH:12]=2)=[O:20])=[CH:5][CH:6]=1

参加物

4

反応物 2

HCID 944Nitric Acid2 回HCID 3035P,P'-dde

生成物 1

HCID 70344,4'-Dichlorobenzophenone

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
20 °C

実験手順

A 200 ml flask equipped with a stirrer was charged with 3.3 g of 1,1-dichloro-2,2-bis(4-chlorophenyl)ethylene and then with 50 ml of an aqueous nitric acid solution having a specific gravity of 1.52. The weight ratio of the reaction material to the aqueous solution of nitric acid was 0.043. While vigorously stirring the resulting mixture at room temperature of about 20° C. in a nitrogen atmosphere, they were reacted for 1 hour. The reaction mixture was thereafter added with water, followed by extraction with dichloromethane. After sufficient washing of the dichloromethane layer with water, the extract was analyzed by gas chromatography. As a result, it was found that 1,1-dichloro-2,2-bis(4-chlorophenyl)ethylene was converted in its entirety to 4,4'-dichloro-3,3'-dinitrobenzophenone, but no 4,4'-dichlorobenzophenone was formed at all.

後処理

  1. customA 200 ml flask equipped with a stirrer
  2. customwere reacted for 1 hour
  3. extractionfollowed by extraction with dichloromethane
  4. washAfter sufficient washing of the dichloromethane layer with water

出典と根拠

ORDレコード
ord-8540449c9a62460284eb2c7c138670d1
出典データセット
uspto-grants-1990_10
特許番号
US04960945

関連ノート

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